potassium carbonate in acetone 5 h; Heating / reflux;

1.1: iron tribromide; bromine; iron / dichloromethane / 8 h / Inert atmosphere; Reflux 2.1: sodium / Inert atmosphere 2.2: 12 h / 110 °C / Inert atmosphere 3.1: ammonium chloride; zinc / methanol; water / 2 h / 20 °C / Inert atmosphere 4.1: hydrogen bromide; copper(I) bromide; lithium bromide; sodium nitrite / tetrahydrofuran / 20 °C / Inert atmosphere; Cooling with ice View Scheme

1.1: sodium / Inert atmosphere 1.2: 12 h / 110 °C / Inert atmosphere 2.1: ammonium chloride; zinc / methanol; water / 2 h / 20 °C / Inert atmosphere 3.1: hydrogen bromide; copper(I) bromide; lithium bromide; sodium nitrite / tetrahydrofuran / 20 °C / Inert atmosphere; Cooling with ice View Scheme

暂无反应条件数据

1: aq. KMnO4 3: Cu, PhI / 202 - 208 °C View Scheme

1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; 2: With boric acid trimethyl ester in tetrahydrofuran; hexane T=-78 - 20°C; 3: With hydrogenchloride in tetrahydrofuran; hexane; water