(1E)-N-羟基-1-苯基-1-丙亚胺合成路线 （共 12 条）
反应条件
1.1: NaH / dimethylformamide / 0 °C 1.2: 82 percent / dimethylformamide / 0 - 20 °C 2.1: BH3*THF; (S)-proline (R)-1,1'-bi(2-naphthyl)dioxyboryl ester / tetrahydrofuran / 48 h / 0 - 5 °C 2.2: aq. HCl / tetrahydrofuran View Scheme
参考文献
Chu, Yunbo; Shan, Zixing; Liu, Dejun; Sun, Nannan
Journal of Organic Chemistry, 2006 , vol. 71, # 10 p. 3998 - 4001
反应条件
NBBTA in tetrachloromethane T=20°C; 3.5 h;
参考文献
Ghorbani-Vaghei, Ramin; Khazaei, Ardeshir
Phosphorus, Sulfur and Silicon and the Related Elements, 2004 , vol. 179, # 6 p. 1169 - 1173
反应条件
S4N4*SbCl5 in toluene T=60°C; Rearrangement; Beckmann rearrangement; 1 h;
参考文献
Heterocycles, , vol. 50, # 1 p. 147 - 157
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Graham,S.H.; Williams,A.J.S.
Tetrahedron, 1965 , vol. 21, p. 3263 - 3272
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Brunner, Henri; Becker, Richard
Angewandte Chemie, 1984 , vol. 96, # 3 p. 221
反应条件
[{Rh(μ-Cl)(1,5-cyclooctadiene)}2]; (4R,5R)-DIOP in benzene T=25°C; 192 h; other catalysator, various times, enantiomeric excess;
参考文献
Brunner, Henri; Becker, Richard
Angewandte Chemie, 1984 , vol. 96, # 3 p. 221
反应条件
1.1: NaH / dimethylformamide / 0 °C 1.2: 82 percent / dimethylformamide / 0 - 20 °C 2.1: BH3*THF; (S)-proline (R)-1,1'-bi(2-naphthyl)dioxyboryl ester / tetrahydrofuran / 48 h / 0 - 5 °C 2.2: aq. HCl / tetrahydrofuran View Scheme
参考文献
Chu, Yunbo; Shan, Zixing; Liu, Dejun; Sun, Nannan
Journal of Organic Chemistry, 2006 , vol. 71, # 10 p. 3998 - 4001
反应条件
sulfuric acid; 1-n-butyl-3-methylimidazolium hexafluorophosphate Beckmann rearrangement; 0.0166667 h; microwave irradiation;
参考文献
Synthetic Communications, , vol. 33, # 13 p. 2301 - 2307
反应条件
S4N4*SbCl5 in toluene T=60°C; Rearrangement; Beckmann rearrangement; 1 h;
参考文献
Heterocycles, , vol. 50, # 1 p. 147 - 157
反应条件
1.1: NaH / dimethylformamide / 0 °C 1.2: 82 percent / dimethylformamide / 0 - 20 °C 2.1: BH3*THF; (S)-proline (R)-1,1'-bi(2-naphthyl)dioxyboryl ester / tetrahydrofuran / 48 h / 0 - 5 °C 2.2: aq. HCl / tetrahydrofuran View Scheme
参考文献
Chu, Yunbo; Shan, Zixing; Liu, Dejun; Sun, Nannan
Journal of Organic Chemistry, 2006 , vol. 71, # 10 p. 3998 - 4001
