1-溴-4-叔丁基环己烯合成路线 （共 11 条）
反应条件
methanesulfonic acid; acetyl-bromide 2 h; Cooling with ice;
参考文献
HUMBOLDT-UNIVERSITAeT zu BERLIN; ARENZ, Christoph; PROKSCH, Denny
Patent: WO2012/150292 A1, 2012 ;
Location in patent: Page/Page column 18-19 ;
反应条件
sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate in dichloromethane 96 h;
参考文献
Napolitano, Elio; Fiaschi, Rita; Mastrorilli, Ettore
Synthesis, 1986 , # 1 p. 122 - 125
反应条件
N-bromosuccinmide in dichloromethane T=25°C; 3 h;
参考文献
Oda, Hiroji; Oshima, Koichiro; Nozaki, Hitosi
Chemistry Letters, 1985 , p. 53 - 56
反应条件
[Cp*Ru(CH3CN)3][SO3CF3]; lithium bromide T=25°C; 0.166667 h; Inert atmosphere;
参考文献
Imazaki, Yusuke; Shirakawa, Eiji; Ueno, Ryota; Hayashi, Tamio
Journal of the American Chemical Society, 2012 , vol. 134, # 36 p. 14760 - 14763
反应条件
[Cp*Ru(CH3CN)3][SO3CF3]; lithium bromide T=25°C; 0.166667 h; Inert atmosphere;
参考文献
Imazaki, Yusuke; Shirakawa, Eiji; Ueno, Ryota; Hayashi, Tamio
Journal of the American Chemical Society, 2012 , vol. 134, # 36 p. 14760 - 14763
反应条件
[Cp*Ru(CH3CN)3][SO3CF3]; lithium bromide T=25°C; 12 h; Inert atmosphere;
参考文献
Imazaki, Yusuke; Shirakawa, Eiji; Ueno, Ryota; Hayashi, Tamio
Journal of the American Chemical Society, 2012 , vol. 134, # 36 p. 14760 - 14763
反应条件
1: 82 percent / BBr3 / CH2Cl2 / 8 h / 0 °C 2: 85 percent / 33percent aq. NaOH / tetrabutylammonium hydrogen sulfate / CH2Cl2 / 96 h View Scheme
参考文献
Napolitano, Elio; Fiaschi, Rita; Mastrorilli, Ettore
Synthesis, 1986 , # 1 p. 122 - 125
反应条件
1: 80 percent / boron trifluoride-diethyl ether / CH2Cl2 / 0.25 h / 0 °C 2: 69 percent / CuBr, KBr / dimethylformamide / 12 h / 25 °C View Scheme
参考文献
Ochiai, Masahito; Sumi, Kenzo; Nagao, Yoshimitsu; Fujita, Eiichi
Tetrahedron Letters, 1985 , vol. 26, # 19 p. 2351 - 2354
反应条件
1: 67 percent / boron trifluoride-diethyl ether / CH2Cl2 / 1.5 h / 0 °C 2: 69 percent / CuBr, KBr / dimethylformamide / 12 h / 25 °C View Scheme
参考文献
Ochiai, Masahito; Sumi, Kenzo; Takaoka, Yoshikazu; Kunishima, Munetaka; Nagao, Yoshimitsu; et al.
Tetrahedron, 1988 , vol. 44, # 13 p. 4095 - 4112
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine; ethylene dibromide hexanes, 1) 1.1) -45 deg C, 30 min, 1.2) 25 deg C, 3 h, 2) 25 deg C, 1.5 h; Yield given. Multistep reaction;
参考文献
Curran, Dennis P.; Jasperse, Craig P.; Totleben, Michael J.
Journal of Organic Chemistry, 1991 , vol. 56, # 25 p. 7169 - 7172
