3-甲基-1-乙酰基-1H-吲哚合成路线 （共 20 条）
反应条件
chiral ferrocene-based; hydrogen; caesium carbonate; [rhodium(I)(norborna-2,5-diene)2]SbF6 in isopropyl alcohol T=80°C; P=38000 Torr; 2 h;
参考文献
Kuwano, Ryoichi; Kashiwabara, Manabu; Sato, Koji; Ito, Takashi; Kaneda, Kohei; Ito, Yoshihiko
Tetrahedron Asymmetry, 2006 , vol. 17, # 4 p. 521 - 535
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in methanol 0.5 h; Heating; Product distribution; Further Variations:Solventsreaction time;
参考文献
Chakrabarty, Manas; Ghosh, Nandita; Khasnobis, Shampa; Chakrabarty, Manju
Synthetic Communications, 2002 , vol. 32, # 2 p. 265 - 272
反应条件
C30H42IrNOP(1+)*C32H12BF24(1-); hydrogen in dichloromethane T=20°C; P=75007.5 Torr; 24 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Baeza, Alejandro; Pfaltz, Andreas
Chemistry - A European Journal, 2010 , vol. 16, # 7 p. 2036 - 2039
反应条件
1: 75 percent / (hexamethylphosphoramide)oxodiperoxomolybdenum (VI) / Ambient temperature 2: 59 percent / concd. H2SO4 / 0 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 32, # 10 p. 3945 - 3951
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in acetonitrile
T=20 - 60°C; Acetylation; 23 h;
参考文献
Kuwano, Ryoichi; Sato, Koji; Kurokawa, Takashi; Karube, Daisuke; Ito, Yoshihiko
Journal of the American Chemical Society, 2000 , vol. 122, # 31 p. 7614 - 7615
反应条件
aluminium trichloride in dichloromethane
T=0°C; 0.5 h;
参考文献
Larock, Richard C.; Yum, Eul Kgun
Journal of the American Chemical Society, 1991 , vol. 113, # 17 p. 6689 - 6690
反应条件
tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide in dichloromethane
T=20°C; 1 h; Inert atmosphere;
参考文献
Pan, Shiguang; Ryu, Naoto; Shibata, Takanori
Journal of the American Chemical Society, 2012 , vol. 134, # 42 p. 17474 - 17477,4
Title/Abstract Full Text Show Details
Pan, Shiguang; Ryu, Naoto; Shibata, Takanori
Journal of the American Chemical Society, 2012 , vol. 134, # 42 p. 17474 - 17477
反应条件
tetrabutyl-ammonium chloride; sodium acetate; palladium diacetate in N,N-dimethyl-formamide
T=80°C; 24 h;
参考文献
Larock, Richard C.; Babu, Srinivasan
Tetrahedron Letters, 1987 , vol. 28, # 44 p. 5291 - 5294
反应条件
chromium dichloride; nickel dichloride in N,N-dimethyl-formamide
T=25°C; 60 h;
参考文献
Hodgson, David M.; Wells, Christopher
Tetrahedron Letters, 1994 , vol. 35, # 10 p. 1601 - 1604
反应条件
1: 70 percent / Pd(OAc)2, LiCl, K2CO3 / dimethylformamide / 12 h / 100 °C
2: 87 percent / AlCl3 / CH2Cl2 / 0.5 h / 0 °C / other reagents
View Scheme
参考文献
Larock; Yum; Refvik
Journal of Organic Chemistry, 1998 , vol. 63, # 22 p. 7652 - 7662
