1,1,2,2-四氟-1-(三氟甲氧基)乙烷合成路线 (共 5 条)
反应条件
sulfur(IV) fluoride; cesium fluoride
参考文献
E. I. du Pont de Nemours and Company
Patent: US6905630 B2, 2005 ;
Location in patent: Page/Page column 5 ;
反应条件
sodium hydroxide T=175 - 345°C;
参考文献
Gubanov, V. A.; Zevakin, I. A.; Gurari, V. E.; Tumanova, A. V.; Dolgopol'skii, I. M.; et al.
Journal of Organic Chemistry USSR (English Translation), 1981 , p. 1409 - 1412
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 8 p. 1587 - 1590
参考文献
Gubanov,V.A. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1964 , vol. 34, p. 2802 - 2803,2825 - 2826
反应条件
(electrochemical fluorination);
参考文献
Berenblit,V.V. et al.
Journal of Organic Chemistry USSR (English Translation), 1976 , vol. 12, p. 765 - 768
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 767 - 770
反应条件
in monofluoro-trichloromethane T=-105°C; competition with ClFC=CFCl and FHC=CF2, relative addition rates and orientation ratios; Rate constantProduct distribution;
参考文献
Navarrini, W.; Russo, A.; Tortelli, V.
Journal of Organic Chemistry, 1995 , vol. 60, # 20 p. 6441 - 6443