2,4,6-三甲基-N-苯基苯胺合成路线 （共 24 条）
反应条件
tris-(dibenzylideneacetone)dipalladium(0); biphenyl-2-yl-di-tert-butyl-phosphane; sodium t-butanolate in toluene
T=100°C; 24 h; Inert atmosphereSealed tube;
参考文献
Hernandez-Perez, Augusto C.; Collins, Shawn K.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12696 - 12700
Angew. Chem., 2013 , vol. 125, # 48 p. 12928 - 12932
反应条件
copper diacetate in dichloromethane
3.5 h; Ambient temperature;
参考文献
Barton, Derek H. R.; Yadav-Bhatnagar, Neerja; Finet, Jean-Pierre; Khamsi, Jamal
Tetrahedron Letters, 1987 , vol. 28, # 27 p. 3111 - 3114
反应条件
copper in dichloromethane
0.75 h; Ambient temperature;
参考文献
Barton, Derek H. R.; Finet, Jean-Pierre; Khamsi, Jamal
Tetrahedron Letters, 1986 , vol. 27, # 31 p. 3615 - 3618
反应条件
1: 2.9 percent / K2CO3, Cu / nitrobenzene / 48 h / 200 °C
2: 70 percent / KOH / various solvent(s) / 24 h / Heating
View Scheme
参考文献
Grellmann, Karl-Heinz; Kuehnle, Wolfgang; Weller, Horst; Wolff, Thomas
Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6889 - 6893
反应条件
1: 2.9 percent / K2CO3, Cu / nitrobenzene / 48 h / 200 °C
2: 70 percent / KOH / various solvent(s) / 24 h / Heating
View Scheme
参考文献
Grellmann, Karl-Heinz; Kuehnle, Wolfgang; Weller, Horst; Wolff, Thomas
Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6889 - 6893
反应条件
in N,N-dimethyl-formamide
T=130°C; 24 h;
参考文献
Carroll, Michael A.; Wood, Reice A.
Tetrahedron, 2007 , vol. 63, # 46 p. 11349 - 11354
反应条件
(1,3-bis(2,6-diisopropylphenyl)imidazolidene)Ni(styrene)2; lithium tert-butylate in 1,4-dioxane
10 h; Inert atmosphereHeatingSchlenk technique;
参考文献
Iglesias, Maria Jose; Blandez, Juan F.; Fructos, Manuel R.; Prieto, Auxiliadora; Alvarez, Eleuterio; Belderrain, Tomas R.; Nicasio, M. Carmen
Organometallics, 2012 , vol. 31, # 17 p. 6312 - 6316
反应条件
copper diacetate in dichloromethane
20 h; Ambient temperatureunder argon;
参考文献
Barton, Derek H. R.; Finet, Jean-Pierre; Khamsi, Jamal
Tetrahedron Letters, 1987 , vol. 28, # 8 p. 887 - 890
反应条件
Cu(II) pivalate in dichloromethane
0.0833333 h; Ambient temperatureother BiV reagents; copper-catalyzed phenylation of amines by BiV reagents; Product distribution;
参考文献
Arnauld, Thomas; Barton, Derek H.R.; Doris, Eric
Tetrahedron, 1997 , vol. 53, # 12 p. 4137 - 4144
反应条件
in N,N-dimethyl-formamide
T=130°C; 24 h; Title compound not separated from byproducts.;
参考文献
Carroll, Michael A.; Wood, Reice A.
Tetrahedron, 2007 , vol. 63, # 46 p. 11349 - 11354
