4-(4-甲基苯基)-2-苯基-1,3-噻唑合成路线 （共 6 条）
反应条件
β-cyclodextrin in water; acetone
T=50°C; 1.5 h;
参考文献
Narender; Somi Reddy; Sridhar; Nageswar; Rama Rao
Tetrahedron Letters, 2005 , vol. 46, # 35 p. 5953 - 5955
反应条件
lithium boron tetrafluoride; 1,10-phenanthroline; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; palladium diacetate in N,N-dimethyl acetamide
T=100°C; 24 h; regioselective reaction;
参考文献
Tani, Satoshi; Uehara, Takahiro N.; Yamaguchi, Junichiro; Itami, Kenichiro
Chemical Science, 2013 , vol. 5, # 1 p. 123 - 135
反应条件
β-cyclodextrin in water; acetone
T=20°C; 2.1 h;
参考文献
Kumar, V. Pavan; Narender; Sridhar; Nageswar; Rao, K. Rama
Synthetic Communications, 2007 , vol. 37, # 24 p. 4331 - 4336
反应条件
1: aq. NaOH / CCl4
2: Ac2O
3: CS2 / acetonitrile
4: aq. H2O2 / formic acid; acetic acid
5: aq. HCl / 200 °C
View Scheme
参考文献
Huisgen,R.; Schmidt,T.
Justus Liebigs Annalen der Chemie, 1978 , p. 29 - 40
反应条件
1: palladium diacetate; copper(l) iodide / N,N-dimethyl-formamide / 40 h / 140 °C
2: palladium diacetate; 1,10-phenanthroline; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; lithium boron tetrafluoride / N,N-dimethyl acetamide / 24 h / 100 °C
View Scheme
参考文献
Tani, Satoshi; Uehara, Takahiro N.; Yamaguchi, Junichiro; Itami, Kenichiro
Chemical Science, 2013 , vol. 5, # 1 p. 123 - 135
反应条件
1: ethanol; water / 3 h / 100 °C / Inert atmosphere
2: 2,2,6,6-tetramethyl-piperidine-N-oxyl; 1,10-phenanthroline; N,N-dimethyl acetamide; palladium diacetate / 48 h / 100 °C / Inert atmosphere
View Scheme
参考文献
Kirchberg, Sylvia; Tani, Satoshi; Ueda, Kirika; Yamaguchi, Junichiro; Studer, Armido; Itami, Kenichiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 10 p. 2387 - 2391
