in acetonitrile-D3 Kinetics; Irradiation (UV/VIS); Degasses condition, 298 K, 71 h;; detected by NMR-spectroscopy;;

iodine in acetonitrile Kinetics; byproducts: {Co(bis(dimethylglyoximato))py(I)}; one-electron oxidn. of Co complex by I2 at 298 K; monitored by (1)H-NMR and UV spect. (361 nm);

in tetrachloromethane Kinetics; Irradiation (UV/VIS); Kinetics of the reaction of Co(CH3)(H3CCNOHONCCH3)2(C5H5N) with I2 under irradiation with light at 517 nm is investigated.; MeI and CoI(H3CCNOHONCCH3)2(C5H5N) are the products.;

in tetrachloromethane Irradiation (UV/VIS); Irradiation at 509 nm in CCl4; Estimation of the quantum yield of the photochemical reaction.;

1: pyridine; CoCl2.6H2O; dmgH2 With sodium hydroxide in methanol; water T=10°C; 0.5 h; Inert atmosphereDarkness; 2: With sodium tetrahydroborate; sodium hydroxide in methanol; water Inert atmosphere; 3: dimethyl sulfate in methanol; water T=0°C; 3 h; Inert atmosphere;

trimethylaluminum; (1R,2R)-naphthylcyclohexylborondichloride in hexane; dichloromethane byproducts: C10H12(CH3)O; addn. of AlMe3 (in hexane) to Co-complex (in CH2Cl2) at -20°C, addn. of ketone and catalyst (in CH2Cl2), stirring (under N2, -20°Cfor 36 h, then 20°C for 2 h); addn. of water and then CH2Cl2, drying (MgSO4), filtration, washing (CH2Cl2), solvent removal (reduced pressure), chromy. (SiO2, Et2O/hexane=1:1, then AcOEt), evapn. (vac.);

in tetrahydrofuran byproducts: C6H8(CH3)(COCH3); AlMe3 in hexanes is added to a soln. of the starting complexes in THF at -10°C under N2, warmed to 25°C, stirred for 30 min; ice is added, the organic layer is dried, the solvent is removed, the oil is chromd.;

in tetrahydrofuran byproducts: C10H9(CH3)(O)2, C10H7(CH3)(O)2; AlMe3 in hexanes is added to a soln. of the starting complexes in THF at 0°C under N2, stirred for 20 min; ice is added, the organic layer is dried, the solvent is removed, the oil is chromd.;

in tetrahydrofuran byproducts: C8H7O(CH3)(O)2; AlMe3 in hexanes is added to a soln. of the starting complexes in THF at -15°C under N2, warmed to 25°C, stirred for 2 h; ice is added, the organic layer is dried, the solvent is removed, the oil is chromd.;

1: C5H5N; NaOH / methanol; water; pyridine 2: tetrahydrofuran 3: tetrahydrofuran View Scheme