三(2,2'-联吡啶)锇(2+)合成路线 （共 10 条）
反应条件
in water
basic soln.;
参考文献
Lebeau, Estelle L.
Journal of Molecular Catalysis A: Chemical, 2004 , vol. 212, # 1-2 p. 83 - 89
反应条件
sodium dithionite in water; ethylene glycol
(N2); refluxing the Os salt and 2,2'-bipyridyl in ethylene glycol for 45min, cooling, addn. of satd. aq. sodium dithionite; filtration, washing (H2O; Et2O); elem. anal.;
参考文献
Griffith, William P.; Reddy, Bharti; Shoair, Abdel G. F.; Suriaatmaja, Maria; White, Andrew J. P.; Williams, David J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1998 , # 7 p. 2819 - 2826
反应条件
sodium hydroxide; Co(2+)*(OH)(1-)={Co(OH)}(1+) in water
outgassing react. solns. under vac. before shaking; mixing and shaking Os-oxidant soln. with sodium hydroxide soln. and CoSO4 soln. (Co(II)/Os(III) 0.1) at 20+/-2°C and pH=11; various product ratio for various conditions; gas chromatographic anal.;
参考文献
Shafirovich, V. Ya.; Khannanov, N. K.; Strelets, V. V.
Nouveau Journal de Chimie, 1980 , vol. 4, p. 81 - 84
反应条件
in water
Kinetics; byproducts: H(1+); 22°C, pH > 4.5; not sepd., detected by UV spectra;
参考文献
Lebeau; Binstead; Meyer
Journal of the American Chemical Society, 2001 , vol. 123, # 43 p. 10535 - 10544
反应条件
in further solvent(s)
Kinetics; byproducts: H(1+); 22°C, pH > 6.2, aq. phosphate buffer; not sepd., detected by UV spectra;
参考文献
Lebeau; Binstead; Meyer
Journal of the American Chemical Society, 2001 , vol. 123, # 43 p. 10535 - 10544
反应条件
in water
Kinetics; 22°C;
参考文献
Nord, Gwyneth; Pedersen, Britta; Floryan-Loevborg, Eva; Pagsberg, Palle
Inorganic Chemistry, 1982 , vol. 21, p. 2327 - 2330
反应条件
in water
Kinetics; stopped-flow apparatus, 25.0°C, ionic strength I = 0.10 M (NaClO4), pH = 4-6 (0.1 M acetate, 0.025 M phosphate, 0.025 M borate buffers);
参考文献
Macartney, Donal H.; Thompson, David W.
Inorganic Chemistry, 1989 , vol. 28, p. 2195 - 2199
反应条件
in water
Kinetics; stopped-flow apparatus, 25.0°C, ionic strength I = 0.10 M (NaClO4), pH = 4-6 (0.1 M acetate, 0.025 M phosphate, 0.025 M borate buffers);
参考文献
Macartney, Donal H.; Thompson, David W.
Inorganic Chemistry, 1989 , vol. 28, p. 2195 - 2199
反应条件
in water
Kinetics; at 22°C;
参考文献
Nord, Gwyneth; Pedersen, Britta; Floryan-Loevborg, Eva; Pagsberg, Palle
Inorganic Chemistry, 1982 , vol. 21, p. 2327 - 2330
反应条件
in ethylene glycol
reaction of Os-complex with two equiv. of org. ligand; chromy. (toluene/acetonitrile); recrystn. (vapor diffusion, ether) from acetonitrile soln.;
参考文献
Richter, Mark M.; Brewer, Karen J.
Inorganica Chimica Acta, 1991 , vol. 180, p. 125 - 132
