potassium fluoride in acetonitrile a) 9 h, -40 deg C, b) 3 h, 18 deg C; other carbonyl compounds, variation of conditions: xfluorinated tertiary alcohols and alkoxides from nucleophilic trifluoromethylation of carbonyl compounds; Mechanism;
参考文献
Kotun, Stefan P.; Anderson, John D. O.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1124 - 1131
byproducts: (CF3)2CO, CF3Cl, Cl2; reaction mixt. maintained at 0°C for 40 h and at room temp. for 94 h and between 25 and 30°C for 6 h; addn. of additional (CF3)3COCl; volatiles removed at room temp. under vac.; elem. anal.;
参考文献
Canich, Joann M.; Gard, Gary L.; Shreeve, Jean'ne M.
Inorganic Chemistry, 1984 , vol. 23, p. 441 - 444
