1: lithium ethanolate; 2-Carboxybenzaldehyde in tetrahydrofuran 2: [(1-phenyl-1-ethenyl)oxy]trimethylsilane in N,N-dimethyl-formamide T=20°C; 2 h; 3: With hydrogenchloride in tetrahydrofuran T=20°C;
in ethanol T=25°C; other ojects of study: metal-ion effects, free energies of metal-ion stabilization of ethoxide ion and of transition states, overall catalytic effects; Rate constantMechanismThermodynamic data;
参考文献
Pregel, Marko J.; Buncel, Erwin
Journal of Organic Chemistry, 1991 , vol. 56, # 19 p. 5583 - 5588
