13H-二苯并(a,i)芴合成路线 （共 19 条）
反应条件
Pd-C; palladium monocarbide in methanol; triethylene glycol dimethyl ether; water
参考文献
Idemitsu Kosan Co., Ltd.
Patent: US2009/267491 A1, 2009 ;
反应条件
potassium hydroxide in methanol
96 h; Heating;
参考文献
Hopkinson, A. C.; Lee-Ruff, E.; Maleki, M.
Synthesis, 1986 , # 5 p. 366 - 371
参考文献
Magidson
Chemische Berichte, 1925 , vol. 58, p. 439
反应条件
aluminium trichloride in benzene
1.) room temperature, 4 h, 2.) reflux, overnight;
参考文献
Regimbald-Krnel, Michele; Wentrup, Curt
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8417 - 8423
反应条件
methanesulfonic acid; palladium on activated charcoal
1.) CHCl3, r.t., 2.) triglyme, reflux; Yield given. Multistep reaction;
参考文献
Harvey, Ronald G.; Pataki, John; Cortez, Cecilia; Raddo, Pasquale Di; Yang, ChengXi
Journal of Organic Chemistry, 1991 , vol. 56, # 3 p. 1210 - 1217
反应条件
1: 1.) Mg or n-C4H9Li / 1.) ether or THF, 2.) reflux, 2 h
2: 80 percent / 96percent H2SO4 / acetic acid / 10 °C
3: 75 percent / 40percent aq. KOH / methanol / 96 h / Heating
View Scheme
参考文献
Hopkinson, A. C.; Lee-Ruff, E.; Maleki, M.
Synthesis, 1986 , # 5 p. 366 - 371
反应条件
1: 1.) Mg or n-C4H9Li / 1.) ether or THF, 2.) reflux, 2 h
2: 80 percent / 96percent H2SO4 / acetic acid / 10 °C
3: 75 percent / 40percent aq. KOH / methanol / 96 h / Heating
View Scheme
参考文献
Hopkinson, A. C.; Lee-Ruff, E.; Maleki, M.
Synthesis, 1986 , # 5 p. 366 - 371
反应条件
phosphoric acid
T=165 - 170°C;
参考文献
Magidson
Chemische Berichte, 1925 , vol. 58, p. 439
反应条件
naphthalene
T=290°C;
参考文献
Franzen,V.; Joschek,H.-I.
Justus Liebigs Annalen der Chemie, 1960 , vol. 633, p. 7 - 13
反应条件
phosphoric acid
1 h; Heatingother reagent: trifluoromethanesulfonic acid;
参考文献
Regimbald-Krnel, Michele; Wentrup, Curt
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8417 - 8423
