1,2-二(2-噻吩基)乙炔合成路线 （共 26 条）
反应条件
in benzene
T=70 - 80°C; Yield given;
参考文献
Carpita, Adriano; Lessi, Alessandro; Rossi, Renzo
Synthesis, 1984 , # 7 p. 571 - 572
反应条件
1: KO-t-Bu; PPh3
2: 87 percent / potassium tert-butoxide / tetrahydrofuran / 20 °C
3: 91 percent / Cu2Cl2; O2; pyridine
View Scheme
参考文献
Rodriguez, J. Gonzalo; Lafuente, Antonio; Rubio, Laura
Tetrahedron Letters, 2004 , vol. 45, # 29 p. 5685 - 5688
反应条件
1: 87 percent / potassium tert-butoxide / tetrahydrofuran / 20 °C
2: 91 percent / Cu2Cl2; O2; pyridine
View Scheme
参考文献
Rodriguez, J. Gonzalo; Lafuente, Antonio; Rubio, Laura
Tetrahedron Letters, 2004 , vol. 45, # 29 p. 5685 - 5688
反应条件
1: n-BuLi, HMDS / tetrahydrofuran; hexane / 1.) -78 deg C, 10 min, 2.) -78 deg C to r.t., 30 min
2: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -60 - 0 °C
View Scheme
参考文献
Mouries, Virginie; Waschbuesch, Rachel; Carran, John; Savignac, Philippe
Synthesis, 1998 , # 3 p. 271 - 274
反应条件
copper(l) iodide; bis(benzonitrile)palladium(II) dichloride; tri-tert-butyl phosphine; diisopropylamine
Inert atmosphere;
参考文献
Tanaka, Yuya; Koike, Takashi; Akita, Munetaka
Chemical Communications, 2010 , vol. 46, # 25 p. 4529 - 4531
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene in water; benzene
18 h; Inert atmosphereSchlenk technique;
参考文献
Tang, Qiuzheng; Xia, Dexin; Jin, Xiqing; Zhang, Qing; Sun, Xiao-Qiang; Wang, Congyang
Journal of the American Chemical Society, 2013 , vol. 135, # 12 p. 4628 - 4631
