3-甲基-4-硝基苯甲酸甲酯合成路线 （共 34 条）
反应条件
thionyl chloride T=0 - 80°C; 1 h;
参考文献
US2012/277224 A1, ;
Page/Page column 33 ;
US 20120277224 A1
反应条件
in hydrogenchloride; methanol
反应条件
tellurium; Bi(NO3)3·5H2O; 5 palladium on charcoal; oxygen in methanol T=25°C; P=760.051 Torr; 8 h;
参考文献
Organic Letters, , vol. 15, # 19 p. 5072 - 5075
反应条件
copper diacetate; acetic anhydride in N,N-dimethyl-formamide; acetonitrile T=130°C; 1 h; Sealed tube;
参考文献
European Journal of Organic Chemistry, , vol. 2014, # 10 p. 2027 - 2031
反应条件
sodium hydrogencarbonate in isobutyramide
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone 1.) THF, -70 deg C, 10 min, 2.) 3 h, 0 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tetrahedron Letters, , vol. 26, # 1 p. 115 - 118
反应条件
1.1: hydrogen / palladium on activated charcoal / methanol / 20 °C 2.1: hydrogenchloride; sodium nitrite; NH4BF4 / water / 0.58 h 2.2: 2 h / 20 °C View Scheme
参考文献
US2012/277224 A1, ;
US 20120277224 A1
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran Heating;
参考文献
Kuethe, Jeffrey T.; Wong, Audrey; Journet, Michel; Davies, Ian W.
Journal of Organic Chemistry, 2005 , vol. 70, # 9 p. 3727 - 3729
反应条件
tetrabutyl ammonium fluoride; N-ethyl-N,N-diisopropylamine in tetrahydrofuran Heating;
参考文献
Kuethe, Jeffrey T.; Wong, Audrey; Journet, Michel; Davies, Ian W.
Journal of Organic Chemistry, 2005 , vol. 70, # 9 p. 3727 - 3729
反应条件
1.1: palladium 10 on activated carbon; ammonium formate / methanol / 3 h / 20 °C / |Inert atmosphere 2.1: potassium acetate / toluene / 0.17 h / |Inert atmosphere; |Reflux 2.2: 16.5 h / |Reflux; |Inert atmosphere View Scheme
参考文献
Hawes, Chris S.; Babarao, Ravichandar; Hill, Matthew R.; White, Keith F.; Abrahams, Brendan F.; Kruger, Paul E.
Chemical Communications, 2012 , vol. 48, # 94 p. 11558 - 11560
