2,2,6-三甲基环己酮合成路线 （共 96 条）
反应条件
toluene-4-sulfonic acid; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in dichloromethane T=100°C; P=60004.8 Torr; 66 h;
参考文献
Keraenen, Mark D.; Kot, Kinga; Hollmann, Christoph; Eilbracht, Peter
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 22 p. 3379 - 3384
反应条件
MABR in dichloromethane T=-40 - -20°C;
参考文献
Maruoka, Keiji; Sato, Junko; Yamamoto, Hisashi
Journal of the American Chemical Society, 1992 , vol. 114, # 11 p. 4422 - 4423
反应条件
lithium diisopropyl amide in tetrahydrofuran; pentane cooling;
参考文献
Jung, Michael E.; Murakami, Masayuki
Organic Letters, 2006 , vol. 8, # 25 p. 5857 - 5859
反应条件
toluene-4-sulfonic acid in water; acetic acid T=20°C; 48 h;
参考文献
Dabdoub, Miguel J.; Silveira, Claudio C.; Lenardao, Eder J.; Guerrero Jr., Palimecio G.; Viana, Luiz H.; Kawasoko, Cristiane Y.; Baroni, Adriano C.M.
Tetrahedron Letters, 2009 , vol. 50, # 40 p. 5569 - 5571
反应条件
1.1: LDA / tetrahydrofuran; hexane / 1 h / 0 °C 1.2: tetrahydrofuran; hexane / 1 h / 23 °C 1.3: 69 percent / methanol; H2O; pyridine / 0.5 h / 105 °C 2.1: 82 percent / aq. HCl / diethyl ether; H2O / 3 h / 23 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 128, # 24 p. 7738 - 7739
反应条件
manganese bromide tetrahydrate; lithium hexamethyldisilazane in tetrahydrofuran 14 h; Ambient temperature;
参考文献
Tetrahedron Letters, , vol. 34, # 46 p. 7395 - 7398
反应条件
manganese bromide tetrahydrate; N,N'-dimethyl-N,N'-propyleneurea; lithium hexamethyldisilazane in tetrahydrofuran T=22°C; 4 h;
参考文献
Tetrahedron Letters, , vol. 34, # 46 p. 7395 - 7398
反应条件
1: H2SO4 2: I2 / Zn-Cu / diethyl ether 3: aq. HCl / methanol View Scheme
参考文献
Journal of the American Chemical Society, , vol. 92, p. 7428 - 7436
反应条件
1: I2 / Zn-Cu / diethyl ether 2: aq. HCl / methanol View Scheme
参考文献
Journal of the American Chemical Society, , vol. 92, p. 7428 - 7436
反应条件
ozone in diethyl ether T=-70°C;
参考文献
Kawamura, Shin-Ichi; Yamakoshi, Hideyuki; Abe, Manabu; Masuyama, Araki; Nojima, Masatomo
Tetrahedron, 2002 , vol. 58, # 5 p. 891 - 896
