3,5,5-三甲基-2-环戊烯-1-酮合成路线 （共 17 条）
反应条件
10 palladium on carbon; hydrogen in ethanol
参考文献
Chapuis, Christian; Saint-Leger, Christine
Helvetica Chimica Acta, 2010 , vol. 93, # 1 p. 111 - 117
反应条件
polyphosphoric acid
T=140°C; 4 h;
参考文献
Chapuis, Christian; Saint-Leger, Christine
Helvetica Chimica Acta, 2010 , vol. 93, # 1 p. 111 - 117
反应条件
sodium hydroxide in water
0.5 h; Heating;
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
反应条件
aluminium trichloride in benzene
T=70°C; 6 h; Yield given;
参考文献
Weyerstahl, Peter; Marschall, Helga; Schulze, Matthias; Schwope, Ina
Liebigs Annales, 1996 , # 5 p. 799 - 807
反应条件
sodium hydroxide in water
4 h; Heating;
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
反应条件
1: 62 percent / Me2AlCl / CH2Cl2 / 18 h / Ambient temperature
2: PCC / CH2Cl2
View Scheme
参考文献
Andersen, Niels H.; Hadley, Stephen W.; Kelly, James D.; Bacon, E. R.
Journal of Organic Chemistry, 1985 , vol. 50, # 21 p. 4144 - 4151
反应条件
PPA
T=90°C; 16 h; Title compound not separated from byproducts;
参考文献
Davis, Chad E; Duffy, Bryan C; Coates, Robert M
The Journal of organic chemistry, 2003 , vol. 68, # 18 p. 6935 - 6943
反应条件
1: 54 percent / 10percent KOH / methanol / 7 h / Heating
2: 77 percent / H2SO4 / 0.42 h / 90 °C
3: 69 percent / NaOH / H2O / 0.5 h / Heating
View Scheme
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
反应条件
(i) aq. H3PO4, (ii) aq. HCl, Cu, Cu2O, hexadecyl-trimethyl-ammonium bromide; Multistep reaction;
参考文献
Kienzle; Minder
Helvetica Chimica Acta, 1976 , vol. 59, # 2 p. 439 - 452
反应条件
1: 75 percent / Na / methanol / 24 h / Heating
2: 54 percent / 10percent KOH / methanol / 7 h / Heating
3: 77 percent / H2SO4 / 0.42 h / 90 °C
4: 69 percent / NaOH / H2O / 0.5 h / Heating
View Scheme
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
