(Z)-2,3-二氯-1,1,1,4,4,4-六氟丁-2-烯合成路线 (共 13 条)
反应条件
chlorine T=300°C; 5 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY; NAPPA, Mario Joseph; SWEARINGEN, Ekaterina N.
Patent: WO2013/32903 A1, 2013 ;
Location in patent: Page/Page column 7-8 ;
反应条件
chlorine T=350°C; 5 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY; NAPPA, Mario Joseph; SWEARINGEN, Ekaterina N.
Patent: WO2013/32903 A1, 2013 ;
Location in patent: Page/Page column 9 ;
反应条件
hydrogen; copper on calcium fluoride T=250 - 450°C; 0.0125 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 6 ;
反应条件
hydrogen; palladium/barium chloride on alumina T=240 - 400°C; 0.00277778 - 0.00833333 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 4-5 ;
反应条件
hydrogen; copper and nickel on carbon T=200 - 375°C; 0.00833333 - 0.0208333 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 5 ;
反应条件
hydrogen; Pd-BaSO4 T=100 - 200°C; 0.0166667 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 4 ;
反应条件
hydrogen; copper/nickel/chromium on calcium fluoride T=350 - 375°C; 0.00833333 - 0.0125 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
hydrogen; palladium on calcium fluoride poisoned with lead acetate T=200 - 300°C; 0.000694444 - 0.00833333 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 8 ;
反应条件
acetic acid; zinc; butan-1-ol T=85 - 95°C;
参考文献
Dickinson et al.
Journal of the Chemical Society, 1958 , p. 1441
反应条件
hydrogen T=180 - 220°C; optical yield given as percent de;
参考文献
Stepanov; Delyagina; Cherstkov
Russian Journal of Organic Chemistry, 2010 , vol. 46, # 9 p. 1290 - 1295