Wilkinson's catalyst in benzene-d6 (N2), HBpin in C6D6 reacted with (E)-2-(p-toluenethio)styrene at room temp. catalyzed by RhCl(PPh3)3 (5 molpercent); not isolated, detected by NMR, chromy.;

Wilkinson's catalyst in benzene-d6 (N2), HBpin in C6D6 reacted with (E)-2-(p-toluenethio)styrene at room temp. catalyzed by RhCl(PPh3)3 (5 molpercent); not isolated, detected by NMR, chromy.;

暂无反应条件数据

Wilkinson's catalyst in toluene (N2), RhCl(PPh3)3 (5 molpercent) in toluene added to (E)-2(p-toluenethio)styrene in toluene, treated dropwise with catecholborane (L:B=1.1.5), reactedat room temp. for 24 h; evapd.(vac.), dissolved (hexane), stored at -30°C, recrystd. twice (hexane);

2: benzene 3: phosphorus (V)-chloride / 200 °C View Scheme