双环[3.2.0]庚-3,6-二烯合成路线 （共 8 条）
反应条件
ammonia; sodium T=-40 - -35°C; 3.5 h;
参考文献
Baldwin, John E.; Belfield, Kevin D.
Journal of Organic Chemistry, 1987 , vol. 52, # 21 p. 4772 - 4776
反应条件
in pentane Irradiation;
参考文献
Srinivasan,R.
Journal of the American Chemical Society, 1972 , vol. 94, # 23 p. 8117 - 8124
反应条件
1: 100 percent Chromat. / Et3N / CH2Cl2 / 7 h / Ambient temperature 2: 67 percent / NH3(liquid), Na / 3.5 h / -40 - -35 °C View Scheme
参考文献
Baldwin, John E.; Belfield, Kevin D.
Journal of Organic Chemistry, 1987 , vol. 52, # 21 p. 4772 - 4776
反应条件
1: 96 percent / NaBH4 / methanol / 21 h / Ambient temperature 2: 100 percent Chromat. / Et3N / CH2Cl2 / 7 h / Ambient temperature 3: 67 percent / NH3(liquid), Na / 3.5 h / -40 - -35 °C View Scheme
参考文献
Baldwin, John E.; Belfield, Kevin D.
Journal of Organic Chemistry, 1987 , vol. 52, # 21 p. 4772 - 4776
反应条件
1: 34.7 g / Et3N / hexane 2: 96 percent / NaBH4 / methanol / 21 h / Ambient temperature 3: 100 percent Chromat. / Et3N / CH2Cl2 / 7 h / Ambient temperature 4: 67 percent / NH3(liquid), Na / 3.5 h / -40 - -35 °C View Scheme
参考文献
Baldwin, John E.; Belfield, Kevin D.
Journal of Organic Chemistry, 1987 , vol. 52, # 21 p. 4772 - 4776
反应条件
pentane T=124.2°C; P=1 Torr; Ea, ΔH*, ΔS*, var. of pressure; Product distributionRate constantThermodynamic data;
参考文献
Roth, Wolfgang R.; Klaerner, Frank-Gerit; Grimme, Wolfram; Koeser, Hans G.; Busch, Ralf; et al.
Chemische Berichte, 1983 , vol. 116, # 8 p. 2717 - 2737
反应条件
in 2,2,4-trimethylpentane T=119.5°C; 1.5 h; Ea, ΔH*, ΔS*; Product distributionThermodynamic dataRate constant;
参考文献
Roth, Wolfgang R.; Klaerner, Frank-Gerit; Grimme, Wolfram; Koeser, Hans G.; Busch, Ralf; et al.
Chemische Berichte, 1983 , vol. 116, # 8 p. 2717 - 2737
反应条件
(i) NOCl, CHCl3, (ii) aq. HCl, 4-oxo-pentanoic acid; Multistep reaction;
参考文献
Jacobson,B.M.; Bartlett,P.D.
Journal of Organic Chemistry, 1973 , vol. 38, p. 1030 - 1041
