11H-10,11-二氮杂苯并[b]芴合成路线 （共 72 条）
反应条件
1: triethylamine / chloroform / 3 h / 20 °C
2: hydrogenchloride; iron; acetic acid / water / 24 h / 120 °C
View Scheme
参考文献
Parvatkar, Prakash T.; Tilve, Santosh G.
Tetrahedron Letters, 2011 , vol. 52, # 49 p. 6594 - 6596
反应条件
1.1: iodine; caesium carbonate / acetonitrile / 9 h / 23 - 25 °C
1.2: 6 h / 23 - 25 °C
2.1: AlCl3, aluminium chloride / benzene / 9 h / Reflux
View Scheme
参考文献
Ali, Shaukat; Li, Ying-Xiu; Anwar, Saeed; Yang, Fang; Chen, Zi-Sheng; Liang, Yong-Min
Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 424 - 431
反应条件
1.1: Oxonereg; / methanol; water / 3 h / 50 °C
2.1: benzoyl chloride; potassium carbonate / dichloromethane; water / 3 h / 0 - 20 °C
3.1: trichlorophosphate / acetonitrile / 3 h / 20 °C / |Reflux
4.1: hydrogenchloride / dichloromethane; diethyl ether / 1 h / 5 - 20 °C
4.2: 5 h / |Reflux
5.1: palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; caesium carbonate / toluene / 1.5 h / 120 °C / |Inert atmosphere; |Microwave irradiation
6.1: bis-triphenylphosphine-palladium(II) chloride; sodium acetate / N,N-dimethyl acetamide / 1 h / 150 °C / |Inert atmosphere; |Microwave irradiation
View Scheme
参考文献
Boganyi, Borbala; Kaman, Judit
Tetrahedron, 2013 , vol. 69, # 45 p. 9512 - 9519
反应条件
1.1: benzoyl chloride; potassium carbonate / dichloromethane; water / 3 h / 0 - 20 °C
2.1: trichlorophosphate / acetonitrile / 3 h / 20 °C / |Reflux
3.1: hydrogenchloride / dichloromethane; diethyl ether / 1 h / 5 - 20 °C
3.2: 5 h / |Reflux
4.1: palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; caesium carbonate / toluene / 1.5 h / 120 °C / |Inert atmosphere; |Microwave irradiation
5.1: bis-triphenylphosphine-palladium(II) chloride; sodium acetate / N,N-dimethyl acetamide / 1 h / 150 °C / |Inert atmosphere; |Microwave irradiation
View Scheme
参考文献
Boganyi, Borbala; Kaman, Judit
Tetrahedron, 2013 , vol. 69, # 45 p. 9512 - 9519
反应条件
1.1: trichlorophosphate / acetonitrile / 3 h / 20 °C / |Reflux
2.1: hydrogenchloride / dichloromethane; diethyl ether / 1 h / 5 - 20 °C
2.2: 5 h / |Reflux
3.1: palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; caesium carbonate / toluene / 1.5 h / 120 °C / |Inert atmosphere; |Microwave irradiation
4.1: bis-triphenylphosphine-palladium(II) chloride; sodium acetate / N,N-dimethyl acetamide / 1 h / 150 °C / |Inert atmosphere; |Microwave irradiation
View Scheme
参考文献
Boganyi, Borbala; Kaman, Judit
Tetrahedron, 2013 , vol. 69, # 45 p. 9512 - 9519
反应条件
1.1: hydrogenchloride / dichloromethane; diethyl ether / 1 h / 5 - 20 °C
1.2: 5 h / |Reflux
2.1: palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; caesium carbonate / toluene / 1.5 h / 120 °C / |Inert atmosphere; |Microwave irradiation
3.1: bis-triphenylphosphine-palladium(II) chloride; sodium acetate / N,N-dimethyl acetamide / 1 h / 150 °C / |Inert atmosphere; |Microwave irradiation
View Scheme
参考文献
Boganyi, Borbala; Kaman, Judit
Tetrahedron, 2013 , vol. 69, # 45 p. 9512 - 9519
参考文献
Engqvist, Robert; Bergman, Jan
Organic Preparations and Procedures International, 2004 , vol. 36, # 4 p. 386 - 390
反应条件
1.1: methylmagnesium bromide / diethyl ether; toluene / 1 h / -5 - 20 °C
1.2: 24 h / -5 - 20 °C
2.1: triphenylphosphine / diphenylether / 4 h / Inert atmosphere; Reflux
View Scheme
参考文献
Kadam, Harik.; Parvatkar, Prakasht.; Tilve, Santosh G.
Synthesis, 2012 , vol. 44, # 9 p. 1339 - 1342
反应条件
hydrogenchloride; tin(ll) chloride
参考文献
De Diesbach et al.
Helvetica Chimica Acta, 1951 , vol. 34, p. 1050,1059
反应条件
1: 76 percent / 0.25 h / Heating
2: 76 percent / N-methylaniline / 3 h / Heating
View Scheme
参考文献
Engqvist, Robert; Bergman, Jan
Organic Preparations and Procedures International, 2004 , vol. 36, # 4 p. 386 - 390
