1,3-双(三丁基甲锡烷基)苯合成路线 （共 7 条）
反应条件
magnesium; ethylene dibromide in tetrahydrofuran T=20°C; Barbier Coupling Reaction; 4 h; SonicationInert atmosphere;
参考文献
Gerbino, Dario C.; Fidelibus, Pablo M.; Mandolesi, Sandra D.; Ocampo, Romina A.; Scoccia, Jimena; Podesta, Julio C.
Journal of Organometallic Chemistry, 2013 , vol. 741-742, # 1 p. 24 - 32
反应条件
magnesium; ethylene dibromide in tetrahydrofuran T=20°C; Barbier Coupling Reaction; 4 h; SonicationInert atmosphere;
参考文献
Gerbino, Dario C.; Fidelibus, Pablo M.; Mandolesi, Sandra D.; Ocampo, Romina A.; Scoccia, Jimena; Podesta, Julio C.
Journal of Organometallic Chemistry, 2013 , vol. 741-742, # 1 p. 24 - 32
反应条件
magnesium; ethylene dibromide in tetrahydrofuran T=35°C; Barbier Coupling Reaction; 1 h; SonicationInert atmosphere;
参考文献
Gerbino, Dario C.; Fidelibus, Pablo M.; Mandolesi, Sandra D.; Ocampo, Romina A.; Scoccia, Jimena; Podesta, Julio C.
Journal of Organometallic Chemistry, 2013 , vol. 741-742, # 1 p. 24 - 32
反应条件
magnesium; ethylene dibromide in tetrahydrofuran T=35°C; Barbier Coupling Reaction; 1 h; SonicationInert atmosphere;
参考文献
Gerbino, Dario C.; Fidelibus, Pablo M.; Mandolesi, Sandra D.; Ocampo, Romina A.; Scoccia, Jimena; Podesta, Julio C.
Journal of Organometallic Chemistry, 2013 , vol. 741-742, # 1 p. 24 - 32
反应条件
tert.-butyl lithium in tetrahydrofuran; pentane stirring (-78°C,1 h), addn. of n-Bu3SnCl, warming, stirring (roomtemp., overnight); quenching with NH4Cl, extn. (Et2O), vacuum distillation; elem. anal.;
参考文献
Koo, Sangho; Liebeskind, Lanny S.
Journal of the American Chemical Society, 1995 , vol. 117, # 12 p. 3389 - 3404
反应条件
bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide
T=100°C; 17 h;
参考文献
Havelkova, Martina; Dvorak, Dalimil; Hocek, Michal
Tetrahedron, 2002 , vol. 58, # 37 p. 7431 - 7435
反应条件
1: 34 percent / Pd(PPh3)2Cl2 / dimethylformamide / 17 h / 100 °C
2: 23 percent / Pd(PPh3)2Cl2 / dimethylformamide / 1 h / 100 °C
View Scheme
参考文献
Havelkova, Martina; Dvorak, Dalimil; Hocek, Michal
Tetrahedron, 2002 , vol. 58, # 37 p. 7431 - 7435
