catalyst: (Ir(OMe)(COD))2/4,4'-(tBu)2-2,2'-bipy in tetrahydrofuran byproducts: H2; 0.2 equiv. of borane reacted with PhBPin in THF at 25°C with (Ir(OMe)(COD))2/4,4'-di-tert-butyl-2,2'-bipyridine (1:2) catalyst system (Ir3 molpercent) for 9 h;
参考文献
Chotana, Ghayoor A.; Rak, Michael A.; Smith, Milton R.
Journal of the American Chemical Society, 2005 , vol. 127, # 30 p. 10539 - 10544
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C / |Inert atmosphere
2: toluene-4-sulfonic acid; sodium nitrite; potassium iodide / water; acetonitrile / 4 h / 10 - 20 °C
View Scheme
参考文献
Tran-Van, Anne-Florence; Huxol, Elena; Basler, Jonathan M.; Neuburger, Markus; Adjizian, Jean-Joseph; Ewels, Chris P.; Wegner, Hermann A.
Organic Letters, 2014 , vol. 16, # 6 p. 1594 - 1597
