[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in benzene (N2); heating mixt. of iridium compd., bipyridine deriv., benzene, dodecane and silylborane deriv. at 80°C for 12 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Boebel, Timothy A.; Hartwig, John F.
Organometallics, 2008 , vol. 27, # 22 p. 6013 - 6019
catalyst:(C5H5)Pd(C3H5)/P(C6H5)3 in toluene reaction of 2.4 equiv. of octyne with boron compd. in toluene in presence of palladium compd. and triphenylphosphine at room temp.; gas chromy.;
参考文献
Ohmura, Toshimichi; Masuda, Kohei; Suginome, Michinori
Journal of the American Chemical Society, 2008 , vol. 130, # 5 p. 1526 - 1527
