1,3-双(2,6-二异丙基苯基)咪唑-2-亚基合成路线 （共 9 条）
反应条件
.eta.(5)-C5H5Fe(.eta.(6)-C6H6); oxygen in THF-d8 (tetrahydrofuran-d8) T=20°C; 0.0166667 h;
参考文献
Mery, Denise; Aranzaes, Jaime Ruiz; Astruc, Didier
Journal of the American Chemical Society, 2006 , vol. 128, # 17 p. 5602 - 5603
反应条件
in tetrahydrofuran T=20°C; 0.5 h; Inert atmosphere;
参考文献
Mendoza-Espinosa, Daniel; Donnadieu, Bruno; Bertrand, Guy
Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7264 - 7265
反应条件
1.1: 77.5 percent / formic acid / ethanol; H2O / 48 h 2.1: toluene / 100 °C 2.2: 47 percent / HCl / toluene; dioxane / 5 h / 70 °C 3.1: 79 percent / KOt-Bu / tetrahydrofuran / 4 h / 20 °C View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 606, # 1 p. 49 - 54
反应条件
1.1: toluene / 100 °C 1.2: 47 percent / HCl / toluene; dioxane / 5 h / 70 °C 2.1: 79 percent / KOt-Bu / tetrahydrofuran / 4 h / 20 °C View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 606, # 1 p. 49 - 54
反应条件
trichlorosilane in toluene T=25°C; 12 h; Inert atmosphere;
参考文献
Ghadwal, Rajendra S.; Roesky, Herbert W.; Merkel, Sebastian; Henn, Julian; Stalke, Dietmar
Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5683 - 5686
Angewandte Chemie, 2009 , vol. 121, p. 5793 - 5796
反应条件
T=-30 - 20°C; 50 h; Inert atmosphere;
参考文献
Schwedtmann, Kai; Holthausen, Michael H.; Feldmann, Kai-Oliver; Weigand, Jan J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 52 p. 14204 - 14208
Angew. Chem., 2013 , vol. 125, # 52 p. 14454 - 14458,5
反应条件
1: 1,2,2-trichloro-1,1,2-trichloro-ethane / tetrahydrofuran / 24 h / -40 - 23 °C 2: cesium fluoride / acetonitrile / 24 h / 60 °C View Scheme
参考文献
PRESIDENT AND FELLOWS OF HARVARD COLLEGE; RITTER, Tobias; TANG, Pingping
Patent: WO2012/142162 A2, 2012 ;
反应条件
1,2,2-trichloro-1,1,2-trichloro-ethane in tetrahydrofuran T=-40 - 23°C; 24 h;
参考文献
PRESIDENT AND FELLOWS OF HARVARD COLLEGE; RITTER, Tobias; TANG, Pingping
Patent: WO2012/142162 A2, 2012 ;
Location in patent: Page/Page column 20-21 ;
参考文献
De Fremont, Pierre; Singh, Rohit; Stevens, Edwin D.; Petersen, Jeffrey L.; Nolan, Steven P.
Organometallics, 2007 , vol. 26, # 6 p. 1376 - 1385
