双环[4.4.1]十一碳-1(10),2,4,6,8-五烯合成路线 （共 33 条）
反应条件
n-butyllithium in diethyl ether; hexane
T=-50 - -10°C;
参考文献
Kitching, William; Olszowy, Henry A.; Schott, Inge; Adcock, William; Cox, D. P.
Journal of Organometallic Chemistry, 1986 , vol. 310, p. 269 - 284
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in 1,4-dioxane
1 h; Heating;
参考文献
Halton, Brian; Russell, Sarah G. G.
Australian Journal of Chemistry, 1992 , vol. 45, # 6 p. 1069 - 1076
反应条件
in gas
T=400°C; P=0.01 Torr; 2.77778E-05 h; Yield given. Yields of byproduct given;
参考文献
Beck, A.; Hunkler, D.; Prinzbach, H.
Tetrahedron Letters, 1983 , vol. 24, # 21 p. 2151 - 2154
反应条件
potassium tert-butylate in dimethyl sulfoxide
16 h; Ambient temperature;
参考文献
Banwell, Martin G.; Papamihail, Con
Journal of the Chemical Society, Chemical Communications, 1981 , # 22 p. 1182 - 1183
反应条件
potassium tert-butylate in dimethyl sulfoxide
Ambient temperature;
参考文献
Banwell, Martin G.; Papamihail, Con
Journal of the Chemical Society, Chemical Communications, 1981 , # 22 p. 1182 - 1183
反应条件
1: With toluene-4-sulfonic acid in toluene
Cyclization; 4 h; Heating;
2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in toluene
Oxidation; 2 h; Heating;
参考文献
Kuroda, Shigeyasu; Zuo, Shengli; Oda, Mitsunori; Fukuta, Atsushi; Kajioka, Takanori; Saito, Toyohiko; Furuta, Shinji; Tsukumo, Hitoshi; Sano, Kenji; Miyatake, Ryuta; Tomoda, Shozo; Hayakawa, Chiharu; Nozawa, Haruna
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 7 p. 1659 - 1671
反应条件
1: 32 percent / NaH / xylene / Heating
2: N-bromosuccinimide / CH2Cl2 / 0.08 h / 0 °C
3: 40 percent / activated copper / tetrahydrofuran / 0.5 h / 90 °C
4: gas / 0 h / 400 °C / 0.01 Torr
View Scheme
参考文献
Beck, A.; Hunkler, D.; Prinzbach, H.
Tetrahedron Letters, 1983 , vol. 24, # 21 p. 2151 - 2154
反应条件
1: N-bromosuccinimide / CH2Cl2 / 0.08 h / 0 °C
2: 40 percent / activated copper / tetrahydrofuran / 0.5 h / 90 °C
3: gas / 0 h / 400 °C / 0.01 Torr
View Scheme
参考文献
Beck, A.; Hunkler, D.; Prinzbach, H.
Tetrahedron Letters, 1983 , vol. 24, # 21 p. 2151 - 2154
反应条件
1: 40 percent / activated copper / tetrahydrofuran / 0.5 h / 90 °C
2: gas / 0 h / 400 °C / 0.01 Torr
View Scheme
参考文献
Beck, A.; Hunkler, D.; Prinzbach, H.
Tetrahedron Letters, 1983 , vol. 24, # 21 p. 2151 - 2154
反应条件
potassium hydroxide in ethanol
参考文献
Kuffner,U.; Schloegl,K.
Monatshefte fuer Chemie, 1972 , vol. 103, p. 1320 - 1336
