N-苄氧羰基-D-苯丙氨酸合成路线 （共 60 条）
反应条件
cell extract of Sphingomonas paucimobilis SC 16113 in water T=42°C; 20 h; Enzymatic reaction;
参考文献
Advanced Synthesis and Catalysis, , vol. 345, # 6-7 p. 830 - 834
反应条件
N-hexadecyl-N,N,N-trimethylammonium bromide; N-acetyl-L-His in water T=25°C; variation of pH, catalyst and their concentration, with an without anionic and non-ionic surfactants; Rate constant;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1483 - 1487
反应条件
1: 74 percent / BuLi; diisopropylamine; HMPA / tetrahydrofuran; hexane / 21 h / -55 °C 2: 85 percent / aq. CF3CO2H / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 60, # 35 p. 7679 - 7692
反应条件
antibody 3G2; Tris buffer; water in dimethyl sulfoxide T=25°C; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 118, # 10 p. 2332 - 2339
反应条件
1: 99 percent / triethylamine; DMAP / CH2Cl2 / 0.5 h / 20 °C 2: 98 percent / sodium azide; 1,4-diaza-bicyclo[2.2.2]octane; 4-dimethylaminopyridine / benzo-15-crown-5 / CH2Cl2 / 20 h / 40 °C 3: 99 percent / hydrogen / Pd/C / methanol / 2 h 4: aq. HCl / 20 h / Heating 5: NaOH; NaHCO3 / H2O / 63 h View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 18 p. 2667 - 2671
反应条件
1: triethylamine / CH2Cl2 / 0.33 h 2: crown ether / dimethylformamide / 66 h 3: NaOH / methanol; H2O / sonication 4: 99 percent / triethylamine; DMAP / CH2Cl2 / 0.5 h / 20 °C 5: 98 percent / sodium azide; 1,4-diaza-bicyclo[2.2.2]octane; 4-dimethylaminopyridine / benzo-15-crown-5 / CH2Cl2 / 20 h / 40 °C 6: 99 percent / hydrogen / Pd/C / methanol / 2 h 7: aq. HCl / 20 h / Heating 8: NaOH; NaHCO3 / H2O / 63 h View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 18 p. 2667 - 2671
反应条件
1: 99 percent / hydrogen / Pd/C / methanol / 2 h 2: aq. HCl / 20 h / Heating 3: NaOH; NaHCO3 / H2O / 63 h View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 18 p. 2667 - 2671
反应条件
1: 98 percent / sodium azide; 1,4-diaza-bicyclo[2.2.2]octane; 4-dimethylaminopyridine / benzo-15-crown-5 / CH2Cl2 / 20 h / 40 °C 2: 99 percent / hydrogen / Pd/C / methanol / 2 h 3: aq. HCl / 20 h / Heating 4: NaOH; NaHCO3 / H2O / 63 h View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 18 p. 2667 - 2671
反应条件
1: NaOH / methanol; H2O / 0.5 h / sonication 2: triethylamine / CH2Cl2 / 0.33 h 3: crown ether / dimethylformamide / 66 h 4: NaOH / methanol; H2O / sonication 5: 99 percent / triethylamine; DMAP / CH2Cl2 / 0.5 h / 20 °C 6: 98 percent / sodium azide; 1,4-diaza-bicyclo[2.2.2]octane; 4-dimethylaminopyridine / benzo-15-crown-5 / CH2Cl2 / 20 h / 40 °C 7: 99 percent / hydrogen / Pd/C / methanol / 2 h 8: aq. HCl / 20 h / Heating 9: NaOH; NaHCO3 / H2O / 63 h View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 18 p. 2667 - 2671
反应条件
1: NaOH / methanol; H2O / sonication 2: 99 percent / triethylamine; DMAP / CH2Cl2 / 0.5 h / 20 °C 3: 98 percent / sodium azide; 1,4-diaza-bicyclo[2.2.2]octane; 4-dimethylaminopyridine / benzo-15-crown-5 / CH2Cl2 / 20 h / 40 °C 4: 99 percent / hydrogen / Pd/C / methanol / 2 h 5: aq. HCl / 20 h / Heating 6: NaOH; NaHCO3 / H2O / 63 h View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 18 p. 2667 - 2671
