1,1-二甲基-2-丙烯基乙酸酯合成路线 （共 69 条）
反应条件
NiCl2TPP; isopropylmagnesium chloride in tetrahydrofuran
T=20°C; 36 h; var. ligands, temp., times; Product distribution;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
反应条件
zinc(II) iodide in dichloromethane
Ambient temperature;
参考文献
Reetz, M. T.; Huettenhain, S.; Huebner, F.
Synthetic Communications, 1981 , vol. 11, # 3 p. 217 - 222
反应条件
sodium tetrahydroborate; NiCl2(TPP)2 in methanol
T=65°C; 36 h;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1986 , vol. 317, p. 383 - 408
反应条件
sodium hydride; triphenylphosphine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
36 h; Heating;
参考文献
Cuvigny, Therese; Julia, Marc; Rolando, C.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 395 - 414
反应条件
triphenyl phosphite; sodium hydride; [Ir(μ-Cl)(1,5-cyclooctadiene)]2 in tetrahydrofuran
2 h; Ambient temperature;
参考文献
Takeuchi; Kashio
Angewandte Chemie - International Edition in English, 1997 , vol. 36, # 3 p. 263 - 265
反应条件
sodium hydride; bis-diphenylphosphinoethane; Pd(1,2-bis(diphenylphosphino)ethane)2 in tetrahydrofuran
36 h; Heating;
参考文献
Cuvigny, Therese; Julia, Marc; Rolando, C.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 395 - 414
反应条件
triphenyl phosphite; sodium hydride; [Ir(μ-Cl)(1,5-cyclooctadiene)]2 in tetrahydrofuran
2 h; Ambient temperature;
参考文献
Takeuchi; Kashio
Angewandte Chemie - International Edition in English, 1997 , vol. 36, # 3 p. 263 - 265
反应条件
Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran
T=65°C; 24 h; Yield given. Yields of byproduct given;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
反应条件
1: 41 percent / CoCl2DPPE, NaBH4 / dimethylformamide / 100 °C
2: NiCl2DPPE, i-PrMgCl / tetrahydrofuran / 36 h / Heating
View Scheme
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
反应条件
methylmagnesium bromide; sodium hydride; NiCl2((PPh3)P)2 in tetrahydrofuran
T=65°C; 36 h; other reag.; other catalyst; other temp./react. time; other solvents; Product distribution;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1986 , vol. 317, p. 383 - 408
