1,1-二甲基-2-丙烯基乙酸酯合成路线 （共 69 条）
反应条件
NiCl2DPPH; isopropylmagnesium chloride in tetrahydrofuran
24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
反应条件
palladium on activated charcoal; Lindlar's catalyst; diethyl ether
Hydrogenation;
参考文献
Nesmejanow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1949 , p. 623,627136,138
Chem.Abstr., 1950 , p. 3920
反应条件
triphenylphosphine in tetrahydrofuran; water
参考文献
Roussel Uclaf
Patent: US4670577 A1, 1987 ;
反应条件
ammonium chloride in tetrahydrofuran
参考文献
Roussel Uclaf
Patent: US4670577 A1, 1987 ;
反应条件
isopropylmagnesium chloride; sodium hydride; NiCl2((CH2)4(PPh3)2)2 in tetrahydrofuran
T=45°C; 24 h; other catalyst; other temp./react. time; other solvent; Product distribution;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1986 , vol. 317, p. 383 - 408
反应条件
tributylphosphine; potassium carbonate; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide
T=20°C; 18 h; Inert atmosphere;
参考文献
Vasil'ev; Lyubimov; Serebryakov; Davankov; Struchkova; Zlotina
Russian Chemical Bulletin, 2010 , vol. 59, # 3 p. 605 - 610
反应条件
1: 41 percent / CoCl2DPPE, NaBH4 / dimethylformamide / 100 °C
2: NiCl2DPPE, i-PrMgCl / tetrahydrofuran / 24 h / Heating
View Scheme
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
反应条件
tetrakis(triphenylphosphine) palladium(0); 18-crown-6 ether; carbon dioxide; potassium carbonate
T=75°C; Tsuji-Trost Allylation; P=129209 Torr; 18 h; Supercritical conditionsAutoclave; Overall yield = 25 percent;
参考文献
Vasil'ev, Andrei A.; Kuchurov, Ilya V.; Zlotin, Sergei G.
Mendeleev Communications, 2013 , vol. 23, # 2 p. 84 - 85
反应条件
NiCl2DPPH; isopropylmagnesium chloride in tetrahydrofuran
24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
