反应条件
n-butyllithium; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane under Ar, 1.6 M hexane soln. of n-BuLi added to suspn. of anhyd. SnCl2 in THF at 0°C, stirred for 20 min, treated with 1.0 M hexane soln. of Et2AlCl at 0°C, stirred for 20 min, mixt. of C3H5OPO(OPh)2 and P(PPh3)4 in THF, stirred for 1 h; poured into 5percent NaOH, extd. with ether, org. layer washed with 5percent NaOH, dried over anhyd. Na2SO4, concd., chromd. (Al2O3, hexane), distd. (bp 120°C (bath temp.)/0.1 Torr);
参考文献
Matsubara, Seijiro; Wakamatsu, Kuni; Morizawa, Yoshitomi; Tsuboniwa, Noriyuki; Oshima, Koichiro; Nozaki, Hitosi
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 4 p. 1196 - 1199
