in acetonitrile
dissolved acylquinone and allylstannane stood for 1 h under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
in dichloromethane
(N2); addn. of Sn-compd. to mixt. of 2.2 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature; treatment with sat. aq. NH4Cl;
参考文献
Marton, Daniele; Tagliavini, Giuseppe; Zordan, Michele; Wardell, James L.
Journal of Organometallic Chemistry, 1990 , vol. 390, # 2 p. 127 - 138
in dichloromethane
(N2); addn. of Sn-compd. to mixt. of 1 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature, standing (4 h); treatment with sat. aq. NH4Cl;
参考文献
Marton, Daniele; Tagliavini, Giuseppe; Zordan, Michele; Wardell, James L.
Journal of Organometallic Chemistry, 1990 , vol. 390, # 2 p. 127 - 138
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
heating in autoclave pressurized with CO2 (33 atm) at 70°C for 24h; cooling, releasing of the pressure, removal of the solvent; chromatography;
参考文献
Shi; Nicholas
Journal of the American Chemical Society, 1997 , vol. 119, # 21 p. 5057 - 5058
