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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
2-氧代己酸
合成路线
（共 30 条）
2492-75-3
2-氧代己酸
→
反应条件
636-36-2
alpha-羟基己酸
反应条件
fructose 1,6-biphosphate; Bacillus stearothermophilus; triethanolamine hydrochloride; Reduced nicotinamide-adenine dinucleotide T=25°C; Rate constantEquilibrium constant;
参考文献
Luyten, Marcel A.; Bur, Daniel; Wynn, Hla; Parris, Wendy; Glod, Marvin; et al.
Journal of the American Chemical Society, 1989 , vol. 111, # 17 p. 6800 - 6804
338-69-2
D-丙氨酸
+
2492-75-3
2-氧代己酸
→
反应条件
327-56-0
D-正亮氨酸
+
127-17-3
丙酮酸
反应条件
pyridoxal 5'-phosphate; recombinant Lactobacillus salivarius UCC118 D-amino acid aminotransferase in aq. phosphate buffer T=30°C; pH=7.5; 0.0166667 h; Enzymatic reaction;
参考文献
Kobayashi, Jyumpei; Shimizu, Yasuhiro; Mutaguchi, Yuta; Doi, Katsumi; Ohshima, Toshihisa
Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 94, p. 15 - 22
338-69-2
D-丙氨酸
+
2492-75-3
2-氧代己酸
→
反应条件
327-56-0
D-正亮氨酸
+
127-17-3
丙酮酸
反应条件
pyridoxal 5'-phosphate; recombinant Lactobacillus salivarius UCC118 D-amino acid aminotransferase in aq. phosphate buffer T=30°C; pH=7.5; 0.0166667 h; Enzymatic reaction;
参考文献
Kobayashi, Jyumpei; Shimizu, Yasuhiro; Mutaguchi, Yuta; Doi, Katsumi; Ohshima, Toshihisa
Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 94, p. 15 - 22
2492-75-3
2-氧代己酸
→
反应条件
327-56-0
D-正亮氨酸
反应条件
meso-2,6-D-diaminopimelic acid dehydrogenase mutant BC621; ammonium chloride; NADPH in various solvent(s) 24 h;
参考文献
Park, Eul-Soo; Dong, Joo-Young; Shin, Jong-Shik
ChemCatChem, 2013 , vol. 5, # 12 p. 3538 - 3542
2492-75-3
2-氧代己酸
→
反应条件
327-57-1
L-正亮氨酸
反应条件
(S)-(+)-2-aminobutyric acid; branched-chain transaminase from Escherichiacoli; S-selective ω-transaminase from Ochrobactrum anthropi; (3-hydroxy-5-hydroxymethyl)-2-methylisonicotinic acid 5-phosphate; isopropylamine in aq. phosphate buffer pH=7; 9 h;
参考文献
Yu, Xuejing; Wang, Xingguo; Engel, Paul C.
FEBS Journal, 2014 , vol. 281, # 1 p. 391 - 400
64-17-5
乙醇
+
2492-75-3
2-氧代己酸
→
反应条件
5753-96-8
2-氧代己酸乙酯
反应条件
sulfuric acid; benzene
参考文献
Nakamura, Kaoru; Inoue, Kiyoko; Ushio, Kazutoshi; Oka, Shinzaburo; Ohno, Atsuyoshi
Journal of Organic Chemistry, 1988 , vol. 53, # 11 p. 2589 - 2593
2492-75-3
2-氧代己酸
→
反应条件
616-06-8
DL-正亮氨酸
反应条件
NADH-H+; potassium chloride; ammonium chloride; hydrogenchloride; Bacillus sphaericus wild type phenylalanine dehydrogenase in various solvent(s) T=25°C; pH=8.0; 0.666667 h;
参考文献
Park, Eul-Soo; Dong, Joo-Young; Shin, Jong-Shik
ChemCatChem, 2013 , vol. 5, # 12 p. 3538 - 3542
2492-75-3
2-氧代己酸
→
反应条件
110-62-3
戊醛
反应条件
NADH-H+; horse liver alcohol dehydrogenase in phosphate buffer T=30°C; pH=6.0; Enzyme kinetics;
参考文献
Bioorganic Chemistry, , vol. 34, # 6 p. 325 - 336
328-50-7
alpha-酮戊二酸
+
327-56-0
D-正亮氨酸
→
反应条件
6893-26-1
D-谷氨酸
+
2492-75-3
2-氧代己酸
反应条件
pyridoxal 5'-phosphate; recombinant Lactobacillus salivarius UCC118 D-amino acid aminotransferase in aq. phosphate buffer T=30°C; pH=7.5; 0.0166667 h; Enzymatic reaction;
参考文献
Kobayashi, Jyumpei; Shimizu, Yasuhiro; Mutaguchi, Yuta; Doi, Katsumi; Ohshima, Toshihisa
Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 94, p. 15 - 22
80465-32-3
→
反应条件
2492-75-3
2-氧代己酸
反应条件
sodium hydroxide in tetrahydrofuran 0.5 h; Ambient temperature;
参考文献
Shin; Yonezawa; Yamada
Chemical and Pharmaceutical Bulletin, 1984 , vol. 32, # 10 p. 3934 - 3944
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