2,4,6-三叔丁基亚硝基苯合成路线 （共 14 条）
反应条件
C19H18N6O2*2Cl(1-)*3H2O*Mn(2+); dihydrogen peroxide in methanol T=45°C; 48 h;
参考文献
Bakshi, Ruchi; Mathur, Pavan
Inorganica Chimica Acta, 2010 , vol. 363, # 13 p. 3477 - 3488
反应条件
(t-BuOO)Co(CH2NCHC6H4O)2 in water; 1,2-dichloro-ethane T=23°C; 0.333333 h; other reagents: 1.) PbO2, 2.) tert-butyl hydroperoxide;
参考文献
Journal of Organic Chemistry, , vol. 61, # 10 p. 3320 - 3326
反应条件
oxygen; macrocyclic Schiff base Fe- in dichloromethane T=20°C; Oxidation; 29 h; Title compound not separated from byproducts;
参考文献
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, , vol. 55, # 1 p. 86 - 93
反应条件
tert.-butylhydroperoxide; cobalt(II)salen in dichloromethane; water Yield given;
参考文献
Foerster, Stefan; Rieker, Anton; Maruyama, Kazushige; Murata, Kunihiko; Nishinaga, Akira
Journal of Organic Chemistry, 1996 , vol. 61, # 10 p. 3320 - 3326
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether inert atmosphere; addn. of org. compd. soln. (THF) to soln. of Ge-compd. (THF/Et2O) at -20°C, keeping at same temp. for 30 min, at room temp. for 1 h; soln. filtration to obtain Ph3GeGePh3, filtrate hydrolysis (HCl), drying (Na2SO4), soln. concn. (reduced pressure); (1)H-NMR and ESR spectroscopy;
参考文献
Riviere, P.; Castel, A.; Desor, D.; Abdennadher, C.
Journal of Organometallic Chemistry, 1993 , vol. 443, # 1 p. 51 - 60
反应条件
base; 2-(α-hydroxyethyl)-3,4-dimethylthiazolium triflate in dichloromethane T=20°C;
参考文献
Ferreira, Luisa M.; Marques, M. Manuel B.; Gloria, Paulo M.C.; Chaves, Humberto T.; Franco, Joao-Pedro P.; Mourato, Isabel; Antunes, Jose-Rafael T.; Rzepa, Henry S.; Lobo, Ana M.; Prabhakar, Sundaresan
Tetrahedron, 2008 , vol. 64, # 33 p. 7759 - 7770
反应条件
in toluene T=-80 - -25°C; 2 h; or in ethyl acetate; Product distributionMechanism;
参考文献
Florjanczyk, Zbigniew; Langwald, Norbert
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 297 - 304
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether inert atmosphere; addn. of org. compd. soln. (THF) to soln. of Ge-compd. (THF/Et2O) at -20°C, keeping at same temp. for 30 min, at room temp. for 1 h; soln. filtration to obtain Ph3GeGePh3, filtrate hydrolysis (HCl), drying (Na2SO4), soln. concn. (reduced pressure); (1)H-NMR and ESR spectroscopy;
参考文献
Riviere, P.; Castel, A.; Desor, D.; Abdennadher, C.
Journal of Organometallic Chemistry, 1993 , vol. 443, # 1 p. 51 - 60
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether inert atmosphere; addn. of org. compd. soln. (THF) to soln. of Ge-compd. (THF/Et2O) at -20°C, keeping at same temp. for 30 min, at room temp. for 1 h, soln. hydrolysis; twice extn. (Et2O), drying (Na2SO4), soln. concn. (reduced pressure); (1)H-NMR and ESR spectroscopy;
参考文献
Riviere, P.; Castel, A.; Desor, D.; Abdennadher, C.
Journal of Organometallic Chemistry, 1993 , vol. 443, # 1 p. 51 - 60
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether inert atmosphere; addn. of org. compd. soln. (THF) to soln. of Ge-compd. (THF/Et2O) at -20°C, keeping at same temp. for 30 min, at room temp. for 1 h; soln. filtration to obtain Ph3GeGePh3, filtrate hydrolysis (HCl), drying (Na2SO4), soln. concn. (reduced pressure); (1)H-NMR and ESR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 443, # 1 p. 51 - 60
