palladium diacetate; triethylamine in 1,4-dioxane under Ar atm.; Schlenk flask charged with Pd(CH3COO)2 and P(C6H11)2(C6H4C6H5); evapd.; filled (Ar); 1,4-dioxane added; stirred for 30 min at room temp.; Et3N added; soln. of bromoindole in dioxane added; neat pinacolborane added; stirred at 80°C; cooled to room temp.; Celite and activated charcoal added; stirred for 15 min; filtered; solvent removed (vac.); residue diluted (cyclohexane); filtered through a short pad of neutral alumina; purified by column chromy. (SiO2, cyclohexane/ethyl acetate);
参考文献
Stadlwieser, Josef F.; Dambaur, Markus E.
Helvetica Chimica Acta, 2006 , vol. 89, # 5 p. 936 - 946
