1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; josiphos in 1,2-dichloro-ethane 24 h; 2: With sodium hydroxide; dihydrogen peroxide in diethyl ether T=0 - 20°C; 2 h; Title compound not separated from byproducts;
参考文献
Crudden, Cathleen M.; Hleba, Yonek B.; Chen, Austin C.
Journal of the American Chemical Society, 2004 , vol. 126, # 30 p. 9200 - 9201
(CF3SO2)2NLi in tetrahydrofuran Electrolysis; electrolysis (2 F/mol) with Mg anode under inert atm. at room temp. at 0.15 A/dm**2; after electrolysis, solvent evapd. under vac.; slowly hydrolysed at 0°C with soln. of H2SO4 until pH 5; purified by column chromy. on silica gel (pentane/ether);
