(CF3SO2)2NLi in tetrahydrofuran Electrolysis; electrolysis (1-4 F/mol) with Mg anode under inert atm. at room temp. at0.15 A/dm**2; after electrolysis, solvent evapd. under vac.; slowly hyd rolysed at 0°C with soln. of H2SO4 until pH 5; purified by column chromy. on silica gel (pentane/ether);
magnesium; triethylamine in tetrahydrofuran Barbier-type reaction; 15 h; Inert atmosphereReflux;
参考文献
Pintaric, Christine; Olivero, Sandra; Gimbert, Yves; Chavant, Pierre Y.; Dunach, Elisabet
Journal of the American Chemical Society, 2010 , vol. 132, # 34 p. 11825 - 11827
Hg, or dibenzo[a,e]cyclooctatetraene, or BHT; trans-chloro(dinitrogen)bis(tri-isopropylphosphine)rhodium(I) in toluene heated at 140°C for 14-80 h with or without reagents (BHT=2,6-(t-butyl)2-4-methyl-C6H3OH); various condns. various product ratio;
参考文献
Shimada, Shigeru; Batsanov, Andrei S.; Howard, Judith A. K.; Marder, Todd B.
Angewandte Chemie - International Edition, 2001 , vol. 40, # 11 p. 2168 - 2171
