1: With lithium bis((trifluoromethyl)sulfonyl)amide in tetrahydrofuran T=20°C; Electrochemical reaction; 2: With sulfuric acid T=0°C; pH=5; Further stages.;
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Laza, Carine; Dunach, Elisabet
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THE REGENTS OF THE UNIVERSITY OF CALIFORNIA; CLARY, Jacob, W.; SINGARAM, Bakthan
Patent: WO2013/16185 A1, 2013 ;
Location in patent: Paragraph 0097-0099 ;
Hg, or dibenzo[a,e]cyclooctatetraene, or BHT; trans-chloro(dinitrogen)bis(tri-isopropylphosphine)rhodium(I) in toluene heated at 140°C for 14-80 h with or without reagents (BHT=2,6-(t-butyl)2-4-methyl-C6H3OH); various condns. various product ratio;
参考文献
Shimada, Shigeru; Batsanov, Andrei S.; Howard, Judith A. K.; Marder, Todd B.
Angewandte Chemie - International Edition, 2001 , vol. 40, # 11 p. 2168 - 2171
[Ir(hydrotris(pyrazolyl)borate)Ir(1,5-cyclooctadiene)] in neat (no solvent) Ir catalyst was added to Schlenk tube; evacuated; backfilled with N2; arene and pinacolborane were added; stirred at 120°C for 18 h; extd. (ether); washed (brine); dried (Na2SO4); concd.; distd.; not septd.;
参考文献
Rentzsch, Christoph F.; Tosh, Evangeline; Herrmann, Wolfgang A.; Kuehn, Fritz E.
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