in n-heptane under dry Ar using standard Schlenk or glove box techniques; soln. of ((C5H4)(BNMe2))2Fe (0.21 mmol) added to soln. of pinacolborane (0.21 mmol); refluxed (ca. 2 h); dried (vac.); residue extd. into hexane; filtered; solvent removed (vac.);
参考文献
Braunschweig, Holger; Gruenewald, Bernd; Schwab, Katrin; Sigritz, Rainer
European Journal of Inorganic Chemistry, 2009 , # 32 p. 4860 - 4863
in deuterated toluene byproducts: [(CH(C(CH3)N(C6H3(CH(CH3)2)2))2)MgH]2; reaction of magnesium compd. with pinacolborane in toluene-d8 at room temp.; NMR;
参考文献
Arrowsmith, Merle; Hill, Michael S.; Hadlington, Terrance; Kociok-Koehn, Gabriele; Weetman, Catherine
Organometallics, 2011 , vol. 30, # 21 p. 5556 - 5559
