1: 76 percent / bis(η4-1,5-cyclooctadiene)di-μ-methoxy-diiridium(I); dtbpy / hexane / 1 h / 60 °C 2: 88 percent / tetrabutylammonium fluoride / tetrahydrofuran / 21 h / 60 °C View Scheme
参考文献
Paul, Sulagna; Chotana, Ghayoor A.; Holmes, Daniel; Reichle, Rebecca C.; Maleczka Jr., Robert E.; Smith III, Milton R.
Journal of the American Chemical Society, 2006 , vol. 128, # 49 p. 15552 - 15553
catalyst: (Ir(C8H12)Cl)2/(NC5H4C(CH3)3-4)2 in tetrahydrofuran react. indole deriv. with boron compds. in THF in the presence of Ir complex and 4,4'-di-tert-butylbipyridine at 80°C for 4 h; workup with 3 M aq. sodium acetate;
参考文献
Robbins, Daniel W.; Boebel, Timothy A.; Hartwig, John F.
Journal of the American Chemical Society, 2010 , vol. 132, # 12 p. 4068 - 4069
Montiel-Palma, Virginia; Lumbierres, Maria; Donnadieu, Bruno; Sabo-Etienne, Slyviane; Chaudret, Bruno
Journal of the American Chemical Society, 2002 , vol. 124, # 20 p. 5624 - 5625
1: With Wilkinson's catalyst in tetrahydrofuran T=20°C; 2.5 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; josiphos in 1,2-dichloro-ethane 24 h; 2: With sodium hydroxide; dihydrogen peroxide in diethyl ether T=0 - 20°C; 2 h; Title compound not separated from byproducts;
参考文献
Crudden, Cathleen M.; Hleba, Yonek B.; Chen, Austin C.
Journal of the American Chemical Society, 2004 , vol. 126, # 30 p. 9200 - 9201
