catalyst:(Ir(COD)OCH3)2/2(4,4'-di-tert-butyl-bipy) in hexane heating in hexane at 25-80°C in the presence of (Ir(OMe)(COD))2/2(4,4'-di-tert-butyl-bipy); (.alpha/β=95/5);
参考文献
Bulletin of the Chemical Society of Japan, , vol. 81, # 12 p. 1535 - 1553
(.eta.5-pentamethylcyclopentadienyl)(.eta.6-hexamethylbenzene)rhodium(I) in further solvent(s) byproducts: H2; as solvent C6H5CF3; at 150°C for 1.5 h; as mixt. of isomers;
参考文献
Cho; Iverson; Smith III
Journal of the American Chemical Society, 2000 , vol. 122, # 51 p. 12868 - 12869
catalyst:(Ir(COD)OCH3)2/2(4,4'-di-tert-butyl-bipy) in hexane heating in hexane at 25-80°C in the presence of (Ir(OMe)(COD))2/2(4,4'-di-tert-butyl-bipy); (.alpha/β=49/51);
参考文献
Miyaura, Norio
Bulletin of the Chemical Society of Japan, 2008 , vol. 81, # 12 p. 1535 - 1553
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
