反应条件
rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate; triphenylphosphine; diazomethyl-trimethyl-silane in 1,4-dioxane; isopropyl alcohol (Ar); addn. of 2-propanol to soln. of Rh(COD)2BF4 and PPh3 in dioxane; addn. of PhCOH; heating at 50°C; addn. of trimethylsilyldiazomethane, TLC analysis; cooling to room temp., addn. dropwise of pinacolborane; stirring overnight; removal of solvent under reduced pressure, flash chromt., GC/MC; as mixt.;
参考文献
Lebel, Helene; Ladjel, Chehla
Journal of Organometallic Chemistry, 2005 , vol. 690, # 23 p. 5198 - 5205