(2E)-2-戊烯-1,5-二醇合成路线 （共 7 条）
反应条件
1: With Pt(dibenzylideneacetone)3; C61H81O4P; 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran T=60°C; 3 h; Inert atmosphereSealed tube; 2: With dihydrogen peroxide; sodium hydroxide in tetrahydrofuran T=0 - 20°C; 4 h; Inert atmosphere; Overall yield = 64 percent; Overall yield = 78 mg; diastereoselective reaction;
参考文献
Coombs, John R.; Haeffner, Fredrik; Kliman, Laura T.; Morken, James P.
Journal of the American Chemical Society, 2013 , vol. 135, # 30 p. 11222 - 11231
反应条件
sulfuric acid T=150°C;
参考文献
Paul; Tchelitcheff
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 224, p. 1722
反应条件
sodium tetrahydroborate
参考文献
Becher,J.
Acta Chemica Scandinavica (1947-1973), 1972 , vol. 26, p. 3627 - 3635
反应条件
1: ethylene glycol; potassium hydroxide 2: aqueous sulfuric acid / 150 °C View Scheme
参考文献
Paul; Tchelitcheff
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 224, p. 1722
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; hydrogen; triphenylphosphine in dichloromethane T=120°C; P=45003.6 Torr; 20 h;
参考文献
Organic Letters, , vol. 4, # 2 p. 289 - 291
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; hydrogen; triphenylphosphine in dichloromethane T=120°C; P=45003.6 Torr; 20 h; Product distribution; Further Variations:ReagentsSolvents;
参考文献
Organic Letters, , vol. 4, # 2 p. 289 - 291
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; hydrogen; triphenylphosphine in dichloromethane T=120°C; P=45003.6 Torr; 20 h; Product distribution; Further Variations:ReagentsSolvents;
参考文献
Organic Letters, , vol. 4, # 2 p. 289 - 291
