2,5-二溴噻吩并[3,2-B]噻吩合成路线 （共 7 条）
反应条件
N-bromosuccinmide in N,N-dimethyl-formamide T=0°C; Inert atmosphere;
参考文献
Dogru, Mirjam; Handloser, Matthias; Auras, Florian; Kunz, Thomas; Medina, Dana; Hartschuh, Achim; Knochel, Paul; Bein, Thomas
Angewandte Chemie - International Edition, 2013 , vol. 52, # 10 p. 2920 - 2924
Angew. Chem., 2013 , vol. 125, # 10 p. 2992 - 2996,5
反应条件
1: potassium carbonate / N,N-dimethyl-formamide 2: sodium hydroxide 3: copper; quinoline 4: N-bromosuccinmide / N,N-dimethyl-formamide View Scheme
参考文献
Molecules, , vol. 17, # 10 p. 12163 - 12171
反应条件
1: sodium hydroxide 2: copper; quinoline 3: N-bromosuccinmide / N,N-dimethyl-formamide View Scheme
参考文献
Molecules, , vol. 17, # 10 p. 12163 - 12171
反应条件
1: copper; quinoline 2: N-bromosuccinmide / N,N-dimethyl-formamide View Scheme
参考文献
Molecules, , vol. 17, # 10 p. 12163 - 12171
反应条件
lithium diisopropyl amide in tetrahydrofuran
参考文献
Biniek, Laure; Schroeder, Bob C.; Donaghey, Jenny E.; Yaacobi-Gross, Nir; Ashraf, Raja Shahid; Soon, Ying W.; Nielsen, Christian B.; Durrant, James R.; Anthopoulos, Thomas D.; McCulloch, Iain
Macromolecules, 2013 , vol. 46, # 3 p. 727 - 735
反应条件
1: 2,5-dibromothienolt;3,2-bgt;thiophene With n-butyllithium in tetrahydrofuran; hexane
T=-70°C; 1 h; Inert atmosphere;
2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane
T=-70°C; Inert atmosphere;
参考文献
Bijleveld, Johan C.; Verstrijden, R. A. Melanie; Wienk, Martijn M.; Janssen, Rene A. J.
Journal of Materials Chemistry, 2011 , vol. 21, # 25 p. 9224 - 9231
反应条件
2: 56 percent / p-toluenesulfonic acid / benzene / 2 h / Heating
3: 87 percent / DDQ / dioxane / 5 h / Heating
View Scheme
参考文献
Mazaki, Yasuhiro; Takiguchi, Naoyoshi; Kobayashi, Keiji
Chemistry Letters, 1991 , # 7 p. 1117 - 1120
