氯 2,3,4,6-四-O-苄基-|á-D-吡喃葡萄糖苷合成路线 （共 32 条）
反应条件
1: 58 percent / KOH / 2 h / 120 °C 2: TiCl4 / CH2Cl2 / 0.08 h / Ambient temperature View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 62, # 11 p. 3549 - 3566
反应条件
1.1: sodium hydride / N,N-dimethyl-formamide; paraffin / 0 °C 1.2: 0 - 20 °C 2.1: N-bromosuccinmide; water / acetone / -45 - 20 °C 3.1: oxalyl dichloride / dichloromethane; N,N-dimethyl-formamide / 1 h / 20 °C View Scheme
参考文献
Beilstein Journal of Organic Chemistry, , vol. 8, p. 413 - 420
反应条件
1.1: methanol; sodium methylate / 20 °C 2.1: sodium hydride / N,N-dimethyl-formamide; paraffin / 0 °C 2.2: 0 - 20 °C 3.1: N-bromosuccinmide; water / acetone / -45 - 20 °C 4.1: oxalyl dichloride / dichloromethane; N,N-dimethyl-formamide / 1 h / 20 °C View Scheme
参考文献
Beilstein Journal of Organic Chemistry, , vol. 8, p. 413 - 420
反应条件
1.1: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C 2.1: methanol; sodium methylate / 20 °C 3.1: sodium hydride / N,N-dimethyl-formamide; paraffin / 0 °C 3.2: 0 - 20 °C 4.1: N-bromosuccinmide; water / acetone / -45 - 20 °C 5.1: oxalyl dichloride / dichloromethane; N,N-dimethyl-formamide / 1 h / 20 °C View Scheme
参考文献
Beilstein Journal of Organic Chemistry, , vol. 8, p. 413 - 420
反应条件
1: N-bromosuccinmide; water / acetone / -45 - 20 °C 2: oxalyl dichloride / dichloromethane; N,N-dimethyl-formamide / 1 h / 20 °C View Scheme
参考文献
Beilstein Journal of Organic Chemistry, , vol. 8, p. 413 - 420
反应条件
titanium tetrachloride in dichloromethane 0.0833333 h; Ambient temperature;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 62, # 11 p. 3549 - 3566
反应条件
1: 58 percent / KOH / 2 h / 120 °C 2: TiCl4 / CH2Cl2 / 0.08 h / Ambient temperature View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 62, # 11 p. 3549 - 3566
反应条件
1: 7 percent / NaH / 1 h / 100 °C 2: TiCl4 / CH2Cl2 / 0.08 h / Ambient temperature View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 62, # 11 p. 3549 - 3566
反应条件
1: 90 percent / tin(IV) chloride / CH2Cl2 / 16 h / 20 °C 2: 1 N sodium methoxide / methanol / 16 h / 20 °C 3: 90.2 percent / 50percent sodium hydride / dimethylformamide; paraffin / 16 h / 20 °C 4: 77 percent / calcium carbonate, mercuric(II) chloride / acetonitrile; H2O / 5 h / Heating 5: thionyl chloride / dimethylformamide; 1,2-dichloro-ethane / 16 h / 20 °C View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 50, # 9 p. 2251 - 2260
反应条件
1: 77 percent / calcium carbonate, mercuric(II) chloride / acetonitrile; H2O / 5 h / Heating 2: thionyl chloride / dimethylformamide; 1,2-dichloro-ethane / 16 h / 20 °C View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 50, # 9 p. 2251 - 2260
