二螺[2.1.2.1]辛烷合成路线 (共 4 条)
反应条件
(.eta.2-methylenecyclopropane)bis(triphenylphosphine)nickel in benzene
T=60°C; 5 h; further reagent Ni(COD)2-PPh3; Further byproducts given. Yields of byproduct given;
参考文献
Furman, D. B.; Kudryashev, A. V.; Isaeva, L. S.; Peganova, T. A.; Ivanov, A. O.; et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, # 6 p. 1132 - 1137
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , vol. 36, # 6 p. 1231 - 1236
反应条件
in toluene
1 h; Ambient temperature;
参考文献
Binger, Paul; Doyle, Michael J.; Benn, Reinhard
Chemische Berichte, 1983 , vol. 116, # 1 p. 1 - 10
反应条件
acrylic acid methyl ester
1) Et2O, 32 deg C, 2 h, 2) toluene, 25 deg C, 4 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Binger, Paul; Doyle, Michael J.; Benn, Reinhard
Chemische Berichte, 1983 , vol. 116, # 1 p. 1 - 10
反应条件
lt;Nilt;P(NEt2)3gt;2gt;x (x gt;=1) in benzene
T=60°C; 7 h; other temperatures, other catalysts; Product distribution;
参考文献
Furman, D. B.; Munshieva, M. K.; Ivanov, A. O.; Belyankin, A. Yu.; Morozova, L. N.; et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 3.1 p. 465 - 469
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 3 p. 541 - 545