2-戊基环己-2-烯-1-酮合成路线 （共 20 条）
反应条件
1: 1) n-BuLi / 1) THF, -78 deg C, 2) THF, -78 deg C
2: 2) 6N HCl / 1) THF, -78 deg C, 3 h, 2a) warming up to room temperature, 2b) 30 min, reflux
View Scheme
参考文献
Savoia; Concialini; Roffia; Tarsi
Journal of Organic Chemistry, 1991 , vol. 56, # 5 p. 1822 - 1827
反应条件
lithium aluminium tetrahydride
参考文献
Ansell,M.F.; Kafka,T.M.
Tetrahedron, 1969 , vol. 25, p. 6025 - 6026
反应条件
1: KOtBu
2: TsOH
3: LiAlH4
View Scheme
参考文献
Ansell,M.F.; Kafka,T.M.
Tetrahedron, 1969 , vol. 25, p. 6025 - 6026
反应条件
1: TsOH
2: LiAlH4
View Scheme
参考文献
Ansell,M.F.; Kafka,T.M.
Tetrahedron, 1969 , vol. 25, p. 6025 - 6026
反应条件
1: KOtBu
2: TsOH
3: LiAlH4
View Scheme
参考文献
Ansell,M.F.; Kafka,T.M.
Tetrahedron, 1969 , vol. 25, p. 6025 - 6026
参考文献
Boeckman,R.K.; Bruza,K.J.
Tetrahedron Letters, 1977 , p. 4187 - 4190
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Baldwin, Jack E.; Adlington, Robert M.; Singh, Rajinder
Tetrahedron, 1992 , vol. 48, # 16 p. 3385 - 3412
反应条件
1: methanol / 1 h
2: sodium acetate, hydroxylamine hydrochloride / ethanol / Ambient temperature
3: pyridine / Ambient temperature
4: 88 percent / TMSOTf / 0 °C
View Scheme
参考文献
Nishiyama, Hisao; Sakuta, Koji; Itoh, Kenji
Tetrahedron Letters, 1984 , vol. 25, # 2 p. 223 - 226
反应条件
1: 90 percent / hydrogen peroxide, potassium hydroxide / methanol; H2O / 1 h / 15 °C
2: 7.8 g / tosyl hydrazine / acetic acid; CH2Cl2 / 8 h / Ambient temperature
3: 2.2 g / tetrahydrofuran / 3 h / Ambient temperature
View Scheme
参考文献
Pramod, Kakumanu; Ramanathan, Halasya; Rao, G. S. R. Subba
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 7 - 10
反应条件
1: 90 percent / hydrogen peroxide, potassium hydroxide / methanol; H2O / 1 h / 15 °C
2: 7.8 g / tosyl hydrazine / acetic acid; CH2Cl2 / 8 h / Ambient temperature
3: 2.2 g / tetrahydrofuran / 3 h / Ambient temperature
4: 1.62 g / pyridine-chromic anhydride complex / CH2Cl2 / 0.25 h / Ambient temperature
View Scheme
参考文献
Pramod, Kakumanu; Ramanathan, Halasya; Rao, G. S. R. Subba
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 7 - 10
