5,10,15,20-四(五氟苯基)卟啉合成路线 （共 31 条）
反应条件
1: With boron trifluoride diethyl etherate in dichloromethane 4 h; RefluxInert atmosphere; 2: With chloranil in dichloromethane 12 h; Reflux;
参考文献
Rei Medical Co., Ltd.
Patent: EP2123664 A1, 2009 ;
Location in patent: Page/Page column 13 ;
反应条件
1: 4-methyl-N-((perfluorophenyl)methylene)benzenesulfonamide With copper(II) bis(trifluoromethanesulfonate) in dichloromethane T=50°C; Inert atmosphere; 2: 5,10-bis(pentafluorophenyl)tripyrromethane in dichloromethane T=50°C; Darkness; 3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane T=50°C;
参考文献
Cinar, Seda; Temelli, Baris; Unaleroglu, Canan
Tetrahedron Letters, 2014 , vol. 55, # 2 p. 544 - 547
反应条件
1: 4-methyl-N-((perfluorophenyl)methylene)benzenesulfonamide With copper(II) bis(trifluoromethanesulfonate) in dichloromethane T=20°C; Inert atmosphere; 2: 5,10-bis(pentafluorophenyl)tripyrromethane in dichloromethane T=20°C; Darkness; 3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane T=20°C;
参考文献
Tetrahedron Letters, , vol. 55, # 2 p. 544 - 547
反应条件
1: 4-methyl-N-((perfluorophenyl)methylene)benzenesulfonamide With copper(II) bis(trifluoromethanesulfonate) in dichloromethane T=20°C; Inert atmosphere; 2: 5,10-bis(pentafluorophenyl)tripyrromethane in dichloromethane T=20°C; Darkness; 3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane T=20°C;
参考文献
Tetrahedron Letters, , vol. 55, # 2 p. 544 - 547
反应条件
1: With boron trifluoride diethyl etherate in chloroform 1 h; DarknessInert atmosphere; 2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in chloroform 1 h;
参考文献
Organic Letters, , vol. 12, # 5 p. 1036 - 1039
反应条件
boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone in chloroform
参考文献
Massachusetts Institute of Technology
Patent: US2011/144324 A1, 2011 ;
Location in patent: Page/Page column 9 ;
反应条件
1: With boron trifluoride diethyl etherate in dichloromethane 2 h; 2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane 10 h;
参考文献
Angewandte Chemie - International Edition, , vol. 40, # 3 p. 619 - 621
反应条件
boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane Further byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 123, # 29 p. 7190 - 7191
反应条件
1: BF3*OEt2 / CHCl3 / 1 h / Ambient temperature 2: p-chloranil / CHCl3 / 1 h / 61 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 54, # 4 p. 828 - 836
反应条件
1: With boron trifluoride diethyl etherate in dichloromethane T=20°C; 4 h; 2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane
参考文献
Geier III, G. Richard; Lindsey, Jonathan S.
Tetrahedron, 2004 , vol. 60, # 50 p. 11435 - 11444
