2,7-二(4,4,5,5-四甲基-1,3,2-二氧硼戊环-2-基)-9,9-十二烷芴合成路线 （共 6 条）
反应条件
n-butyllithium in tetrahydrofuran
T=-78°C; Miyaura coupling;
参考文献
Dudek, Stephen P.; Pouderoijen, Maarten; Abbel, Robert; Schenning, Albertus P. H. J.; Meijer
Journal of the American Chemical Society, 2005 , vol. 127, # 33 p. 11763 - 11768
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate in 1,4-dioxane; N,N-dimethyl-formamide
T=80°C; 12 h;
参考文献
Guo, Zengshan; Liu, Deang; Wang, Cheng; Pei, Jian; Zhou, Zhanglin; Zhao, Lihua; Gibson, Gary; Brug, James; Lam, Sity; Mao, Samuel S.
Science China Chemistry, 2011 , vol. 54, # 4 p. 678 - 684
反应条件
1: 46 percent / aq. NaOH; benzyltriethylammonium chloride / dimethylsulfoxide
2: 77 percent / nBuLi / tetrahydrofuran / -78 °C
View Scheme
参考文献
Dudek, Stephen P.; Pouderoijen, Maarten; Abbel, Robert; Schenning, Albertus P. H. J.; Meijer
Journal of the American Chemical Society, 2005 , vol. 127, # 33 p. 11763 - 11768
反应条件
1: 46 percent / aq. NaOH; benzyltriethylammonium chloride / dimethylsulfoxide
2: 77 percent / nBuLi / tetrahydrofuran / -78 °C
View Scheme
参考文献
Dudek, Stephen P.; Pouderoijen, Maarten; Abbel, Robert; Schenning, Albertus P. H. J.; Meijer
Journal of the American Chemical Society, 2005 , vol. 127, # 33 p. 11763 - 11768
反应条件
1.1: tetrabutylammomium bromide; sodium hydroxide / water / 0.25 h / 60 °C / Inert atmosphere
1.2: Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -80 °C / Inert atmosphere
2.2: 4 h / 20 °C / Inert atmosphere
View Scheme
参考文献
Grisorio, Roberto; Allegretta, Giovanni; Mastrorilli, Piero; Suranna, Gian Paolo
Macromolecules, 2011 , vol. 44, # 20 p. 7977 - 7986
反应条件
1: bromine; iron / chloroform / 0 °C
2: tetrabutylammomium bromide / tetrahydrofuran
3: n-butyllithium / -78 °C
View Scheme
参考文献
Lo, Chih-Nan; Hsu, Chain-Shu
Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 15 p. 3355 - 3365
