in gas
Electric Arc; passing a pulsed electric discharge through a gas mixt. contg. SF6 and NO under an atmosphere of 2 atm Ar;
参考文献
Styger, Christian; Gatehouse, Bethany; Heineking, Nils; Jaeger, Wolfgang; Gerry, Michael C. L.
Journal of the Chemical Society, Faraday Transactions, 1993 , vol. 89, # 12 p. 1899 - 1902
glass in neat (no solvent)
byproducts: H2SiF6, H2SiO3; red heat;;
参考文献
Moissan, H.; Lebeau, S.
Ann. Chim. Phys., 1902 , vol. 26, p. 145 - 178
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Moissan, H.; Lebeau, S.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1900 , vol. 130, p. 865 - 871
hydrogen; nitrogen(IV) oxide in neat (no solvent)
Kinetics; (He); react. of SF6 (producing F) with H2 and HBr in a fast-flow system, NO2 as scavenger of hydrogen atoms; monitored by MAS;
参考文献
Edrei, Rachel; Persky, Avigdor
Chemical Physics Letters, 1989 , vol. 157, p. 265 - 270
glass in neat (no solvent)
byproducts: H2SiF6, SiO2 hydrate; Electrochem. Process; electric sparks (discharge) in glass vessel; formation of S, H2SiO4 and SiO2 hydrate caused by glass;;
参考文献
Moissan, H.; Lebeau, S.
Ann. Chim. Phys., 1902 , vol. 26, p. 145 - 178
Full Text Show Details
Moissan, H.; Lebeau, S.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1900 , vol. 130, p. 865 - 871
Beattie, W. H.; Arnold, G. P.; Wenzel, R. G.
Chemical Physics Letters, 1972 , vol. 16, p. 164 - 168
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Gmelin Handbook: F: SVol.3, 2.1.8.3, page 124 - 126
Kinetics; selected ion flow tube technique at 300 +/- 5 K;;
参考文献
Petrie, Simon; Freeman, Colin G.; Meot-Ner, Michael; McEwan, Murray J.; Ferguson, Eldon E.
Journal of the American Chemical Society, 1990 , vol. 112, # 20 p. 7121 - 7126
in neat (no solvent)
byproducts: Br; Irradiation (UV/VIS); pulsed laser photolysis of mixt. of 20percent SF6 and 10percent HBr in Ar (F atoms generation); spectrally and time resolved chemiluminescence mapping;
参考文献
Feezel, L. L.; Tardy, D. C.
Journal of Physical Chemistry, 1989 , vol. 93, # 8 p. 3124 - 3129