2,4,6,8-四甲基-2,4,6,8-四乙烯基环四硅氧烷合成路线 （共 38 条）
反应条件
1: D4v With tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 0.166667 h;
2: 4'-iodoacetophenone With bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=20°C; 0.166667 h;
参考文献
Denmark, Scott E.; Wang, Zhigang
Journal of Organometallic Chemistry, 2001 , vol. 624, # 1-2 p. 372 - 375
反应条件
1: D4v With triphenyl-arsane; tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 0.166667 h;
2: methyl 2-iodobenzoate With bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=20°C; 8 h;
参考文献
Denmark, Scott E.; Wang, Zhigang
Journal of Organometallic Chemistry, 2001 , vol. 624, # 1-2 p. 372 - 375
反应条件
tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0); biphenyl-2-yl-di-tert-butyl-phosphane in tetrahydrofuran
T=60°C; 17 h; Inert atmosphere;
参考文献
Jaeger, Michael; Goerls, Helmar; Guenther, Wolfgang; Schubert, Ulrich S.
Chemistry - A European Journal, 2013 , vol. 19, # 6 p. 2150 - 2157
反应条件
tetrabutyl ammonium fluoride; palladium (II) bromide; biphenyl-2-yl-di-tert-butyl-phosphane in tetrahydrofuran
T=50°C; 17 h;
参考文献
Denmark, Scott E.; Butler, Christopher R.
Organic Letters, 2006 , vol. 8, # 1 p. 63 - 66
反应条件
1: D4v With tetrabutyl ammonium fluoride; palladium (II) bromide; biphenyl-2-yl-di-tert-butyl-phosphane in tetrahydrofuran
T=20°C; 0.25 h; Inert atmosphere;
2: 3-(bromo)-quinoline in tetrahydrofuran
T=50 - 62°C; 2.83333 h; Inert atmosphere;
参考文献
Denmark, Scott E.; Butler, Christopher R.; Pfaltz, Andreas; Woodmansee, David H.
Organic Syntheses, 2009 , vol. 86, p. 274 - 286
反应条件
tetrabutyl ammonium fluoride; palladium (II) bromide; biphenyl-2-yl-di-tert-butyl-phosphane in tetrahydrofuran
T=50°C; 2 h;
参考文献
Denmark, Scott E.; Butler, Christopher R.
Organic Letters, 2006 , vol. 8, # 1 p. 63 - 66
反应条件
tetrabutyl ammonium fluoride; palladium (II) bromide; biphenyl-2-yl-di-tert-butyl-phosphane in tetrahydrofuran
T=50°C; 12 h;
参考文献
Denmark, Scott E.; Butler, Christopher R.
Organic Letters, 2006 , vol. 8, # 1 p. 63 - 66
反应条件
tetrabutyl ammonium fluoride; palladium (II) bromide; biphenyl-2-yl-di-tert-butyl-phosphane in tetrahydrofuran
T=50°C; 24 h; Title compound not separated from byproducts;
参考文献
Denmark, Scott E.; Butler, Christopher R.
Organic Letters, 2006 , vol. 8, # 1 p. 63 - 66
