1-乙炔基-2-丙二烯基苯合成路线 （共 7 条）
反应条件
o-nitrobenzenesulfonyl hydrazide; triphenylphosphine; diethylazodicarboxylate in tetrahydrofuran T=20°C; Isomerization; deoxygenation; 8 h;
参考文献
Hughes, Thomas S.; Carpenter, Barry K.
Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 11 p. 2291 - 2298
反应条件
1: NEt3 / CuI; Pd(PPh3)2Cl2 / diethyl ether 2: diethyl ether 3: 90 percent / potassium carbonate / methanol / 0.33 h / 20 °C 4: 46.3 percent / DEAD; PPh3; o-nitrobenzenesulfonylhydrazine / tetrahydrofuran / 8 h / 20 °C View Scheme
参考文献
Hughes, Thomas S.; Carpenter, Barry K.
Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 11 p. 2291 - 2298
反应条件
1: diethyl ether 2: 90 percent / potassium carbonate / methanol / 0.33 h / 20 °C 3: 46.3 percent / DEAD; PPh3; o-nitrobenzenesulfonylhydrazine / tetrahydrofuran / 8 h / 20 °C View Scheme
参考文献
Hughes, Thomas S.; Carpenter, Barry K.
Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 11 p. 2291 - 2298
反应条件
1: 90 percent / potassium carbonate / methanol / 0.33 h / 20 °C 2: 46.3 percent / DEAD; PPh3; o-nitrobenzenesulfonylhydrazine / tetrahydrofuran / 8 h / 20 °C View Scheme
参考文献
Hughes, Thomas S.; Carpenter, Barry K.
Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 11 p. 2291 - 2298
反应条件
in dimethyl sulfoxide; toluene T=100°C; Pauson-Khand reaction; 8 h; Product distribution; Further Variations:TemperaturesReagentsSolvents;
参考文献
Tetrahedron Letters, , vol. 46, # 46 p. 7985 - 7988
反应条件
T=90°C; Addition; Myers-Saito cycloaromatization; hydrogenation; Product distribution;
参考文献
Journal of the Chemical Society. Perkin Transactions 2, , # 11 p. 2291 - 2298
反应条件
T=90°C; Addition; Myers-Saito cycloaromatization; hydrogenation; Product distribution;
参考文献
Journal of the Chemical Society. Perkin Transactions 2, , # 11 p. 2291 - 2298
